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MCAT Review > Organic Chemistry > Flashcards

Organic Chemistry Flashcards

(58 cards)

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1
Q

Methyl Polar Protic

A

Sn2

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2
Q

Primary Polar Protic

A

Sn2

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3
Q

Secondary Polar Protic

A

Sn1/E1

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4
Q

Tertiary Polar Protic

A

Sn1/E1

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5
Q

Methyl Polar Aprotic

A

Sn2

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6
Q

Primary Polar Aprotic

A

Sn2

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7
Q

Secondary Polar Aprotic

A

Sn2

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8
Q

Tertiary Polar Aprotic

A

Sn1/E1

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9
Q

Methyl Strong Small Base

A

Sn2

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10
Q

Primary Strong Small Base

A

Sn2

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11
Q

Secondary Strong Small Base

A

E2

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12
Q

Tertiary Strong Small Base

A

E2

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13
Q

Methyl Strong Bulky Base

A

Sn2

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14
Q

Primary Strong Bulky Base

A

E2

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15
Q

Secondary Strong Bulky Base

A

E2

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16
Q

Tertiary Strong Bulky Base

A

E2

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17
Q

Polar Protic Solvents

A

Acetic Acid, H2O, ROH, NH3

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18
Q

Polar Aprotic Solvents

A

DMF, DMSO, Acetone, Ethyl Acetate

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19
Q

PCC

A

Oxidizes 1° alcohols to aldehydes
Oxidizes 2° alcohols to keytones

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20
Q

KMnO4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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21
Q

H2Cr2O4

A

Oxidizes 1° alcohols to carboxylic acids
Oxidizes 2° alcohols to keytones

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22
Q

NaBH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols

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23
Q

LiAlH4

A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

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24
Q

LiAlH4

Study These Flashcards
A

Reduces aldehydes to 1° alcohols
Reduces keytones to 2° alcohols
Reduces carboxylic acids to 1° alcohols
Reduces esters to 2° alcohols

25
N-H IR Peak
Sharp 3300
26
O-H IR Peak
Broad 300-3300
27
Triple Bond CO/CN
Medium 1900-2200
28
CO Double Bond IR
Sharp 1750
29
CC Double Bond
Weak 1600-1680
30
Formyl Group
31
Formaldehyde
32
Formic Acid
33
Acetyl group
34
Acetaldehyde
35
Acetic Acid
36
Acetone
37
Acetylacetone
38
Acetophenone
39
Benzyl Group
40
Benzaldehyde
41
Benzoic Acid
42
Benzoin
43
Styrene
44
Acryl Group
45
Acrolein
46
Acrylic Acid
47
Carboxyl Group
48
Carboxylate Ion
49
Carbonate Ion
50
Carbonic Acid
51
Cation-Exchange Chromatography
Has negative charged beads and attracts cations.
52
Affinity Chromatography
Uses a bound receptor or ligand and an eluent with free ligand or a receptor for the protein of interest. Histidine Tags are a good example.
53
Pyrrole
54
Short Chain Fatty Acids
55
Amide
56
Amine
57
Imine
58
Enamine

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