Organic Chemistry Flashcards
(26 cards)
Carbon Structure
Symbol C
Group 14
Atomic number 6
Atomic mass 12.01
Number of protons 6
Number of neutrons 6
Number of electrons 6
Electron arrangement 2,4
Bonding Covalent
Molecular Formula
Notation used to show the type and number of atoms in a molecule.
Condensed Structural Formula
Notation used to show the type and number of atoms in a molecule, with groups of atoms with the molecule written separately.
Structural Formula
Graphical representation of a molecule, showing the type and number of atoms and how they are bonded.
Homologous Series
A homologous series is a group of organic molecules from the same family of organic molecules that share the same general formula, and have similar chemical properties.
- Alkanes
- Alkenes
-Alcohols
Alkanes
General Formula: CnH2n+2
Alkanes are a homologous series of hydrocarbons. characterise by having carbon atoms linked with single bonds. They all have the suffix -ane. Are saturated molecules. If any atoms are added to an alkane one atom must be removed first. This reaction knows as a substitution reaction. There needs to be enough energy (heat or UV light) must be available to overcome the activation energy required to break the strong C-H ho
Alkenes
General Formula: CnH2n
Alkenes are a homologous series of hydrocarbons, characterise by having carbon atoms linked with one or more double bonds. They all have the suffix -ene. Are unsaturated molecules. If another atoms is added to an alined the double nod can be broken down to single bond and the available site can occupied by another atom. This reaction is known as an addition reaction. This reactions requires lower activation energy to break the double bond.
Alcohols
General Formula: CnH2n+1OH
Alcohol are not hydrocarbons as they contain oxygen in addition to carbon and hydrogen atoms. The suffix is -anol. They are used as solvents and fuels and ethanol, a two carbon alcohol, is used to drink.
Solute
A substance that can dissolve in a solvent.
Solvent
The liquid that dissolves the solute.
Solution
When a solute dissolves in a solvent.
Soluble
The solid substance being dissolved.
Insoluble
A substance that cannot dissolve in a solvent.
Miscible
Two liquids that can dissolve into each other.
Immiscible
Two liquids that cannot dissolve into each other.
Melting and Boiling Points for alkanes
The more carbon atoms the higher the boiling point. The more carbon atoms in a molecule, the stonger the intermolecular forces which means they require more energy to break them apart and turn them into a gas.
Methane to Butane is a gas at room temperature.
Pentane to decane is a liquid at room temperature.
Complete combustion
Occurs in a plentiful tuple of oxygen. All carbon and hydrocarbon atoms
are oxidise to carbon dioxide (CO2) and water (H2O).
Fuel + Oxygen ==> Carbon dioxide + Water
Incomplete combustion
Occurs in a limited supply of oxygen. Hydrogen atoms are oxides to water (H2O). Carbon products include carbon monoxide (CO) and carbon/soot (C)
Fuel + Oxygen ==> Carbon Monoxide + Water
or
Fuel + Oxygen ==> Carbon + Water
Effects of combustion products on human health
Carbon monoxide is dangerous because it is colourless, odourless and very toxic since it competes with oxygen for the haemoglobin which is alter released when it arrives at the cells. When carbon monoxide is inhaled and enters the bloodstream it binds more than oxygen. This causes a lack of oxygen in the cells and causes body tissues and cells to die, leading to death.
Carbon can effect your respiratory system.
Effects of combustion products on the environment
- Greenhouse Effect
- Global Warming
-Acid Rain
-Carbon Monoxide
-Soot
-Fuels
-Biomass Energy
-Non-Renewable Energy
-Fossil Fuels (Coal, Oil and Gas)
Fractional Distillation
In a fractional distillation, a mixture of liquids is boiled and the resulting vapors travel up a glass tube called a “fractionating column” and separate.
Coolest at the top (gases)
Lowest boiling points which is why they don’t condense (gases)
Hottest at bottom
Large molecules condense here as they have the highest boiling points.
Fractions of Crude Oil and their uses
Bottom to top (Hottest to Coolest)
Bitumen (asphalt/road)
Lubricant Oil (wax)
Fuel Oil (factories)
Diesel (trucks)
Paraffin (fuel for airplanes)
Naphtha (cleaning fluids)
Gasoline (fuel in cars)
Petroleum Gas (cooking)
Cracking
Breaking long chained molecules into shorter, and more useful products such as petrol or to make ethene, that can be made into plastics. The process involves heat and a catalyst.
Monomer
Small molecules (alkenes) which join to form polymers.