Organic Chemistry Flashcards

(48 cards)

1
Q

What is a hydrocarbon?

A

A compound of hydrogen and carbon only

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2
Q

What is a saturated hydrocarbon?

A

A hydrocarbon containing no double C bonds

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3
Q

What is an unsaturated hydrocarbon

A

A hydrocarbon containing double C bonds

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4
Q

What is general formula

A

An algebraic formula that can describe any member of a family of compounds

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5
Q

What is empirical formula

A

The simplest whole number ratio of atoms of each element in a compound

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6
Q

What is molecular formula

A

The actual number of atoms of each element in a molecule

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7
Q

What does displayed formula show

A

How all the atoms are arranged and all the bonds between them

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8
Q

What does structural formula show

A

The arrangement of atoms carbon by carbon with the attached hydrogens and functional groups

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9
Q

What is a homologous series

A

A group of compounds that can all be represented by the same general formula

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10
Q

Do compounds in a homologous series share similar chemical properties?

A

Yes

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11
Q

What is the general formula for alkanes?

A

CₙH₂ₙ₊₂

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12
Q

What is the general formula for alkenes?

A

CₙH₂ₙ

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13
Q

What is a functional group?

A

A group of atoms that determine how a compound typically reacts

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14
Q

What is isomerism?

A

Isomerism is when compounds have the same molecular formula but different structures

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15
Q

What is the stem for 1 carbon

A

Meth

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16
Q

What is the stem for 2 carbon

A

Eth

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17
Q

What is the stem for 3 carbon

A

Prop

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18
Q

What is the stem for 4 carbon

A

But

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19
Q

What is the stem for 5 carbon

A

Pent

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20
Q

What is the stem for 6 carbon

21
Q

What is an isomer

A

A molecule with the same molecular formula but different displayed formula

22
Q

What is crude oil

A

A mixture of hydrocarbons

23
Q

How is crude oil separated into different fractions?

A

Crude oil is heated and vaporized. In a fractional distillation column, different fractions condense at different levels based on boiling points

24
Q

What is bitumen used for

A

Surfacing roads
Roofs

25
What is fuel oil used for
Fuel for ships and power stations
26
What is diesel used for
Fuel in cars / larger vehicles
27
What is kerosene used for
Aircraft fuel
28
What is gasoline used for
Fuel in cars
29
What is refinery gases used for
Domestic heating and cooking
30
What is the trend in colour when the fractions of crude oil are burned?
As you go down, the fractions get darker. This happens because heavier fractions have larger, more complex molecules that absorb more light.
31
Explain the trend in boiling point for the fractions of crude oil
Boiling points increase as you go down. Lighter fractions have lower boiling points because their smaller molecules need less energy to separate, while heavier fractions need more energy due to larger molecules
32
Explain the trend in viscosity for the fractions of crude oil
Viscosity increases as you go down. Lighter fractions are less viscous, while heavier ones are thicker due to stronger intermolecular forces between larger molecules
33
Explain the trend in cleanliness of the flame when burning the fractions of crude oil
Cleanliness decreases as you go down. Lighter fractions burn cleanly with a blue flame, while heavier ones burn with a yellow, smoky flame because they have more carbon and produce soot
34
What is fuel
A substance that, when burned, releases heat energy
35
What is the formula for the complete combustion of hydrocarbons
hydrocarbon + oxygen -> carbon dioxide + water
36
What is the formula for the incomplete combustion of hydrocarbons
Hydrocarbon + Oxygen → Carbon monoxide + Carbon (soot) + Water
37
When are nitrogen oxides created
When the temperature is high enough for the nitrogen an d oxygen in the air to react (i.e. inside car engines)
38
How does the combustion of some impurities in hydrocarbon fuels result in the formation of sulfur dioxide?
Hydrocarbons with sulfur impurities release sulfur when burned. The sulfur reacts with oxygen in the air to form sulfur dioxide (SO₂), a harmful gas
39
How do sulfur dioxide and nitrogen oxides contribute to acid rain?
When sulfur dioxide and nitrogen oxides mix with water vapour in clouds they form dilute sulfuric acid and nitric acid
40
What is cracking?
A form of thermal decomposition in which large hydrocarbons are broken down into smaller hydrocarbons
41
Describe catalytic cracking
Vaporised hydrocarbons are passed over a powdered catalyst (600-700 degrees). Silica or alumina used as catalyst.
42
Why is cracking used
Demand for short-chain hydrocarbons is much higher than large-chain Some hydrocarbons are not found in crude oil but can be obtained through cracking
43
Are alkenes more valuable than alkanes?
Yes
44
Why are alkenes more valuable than alkanes?
Alkenes are more reactive and can be used to make products like plastics, while alkanes are mainly used as fuels
45
Describe the reaction of alkanes with halogens in ultraviolet radiation
Undergo a substitution reaction, where a hydrogen atom is replaced by a halogen atom
46
What is the functional group in alkenes?
C=C
47
Describe the reactions of alkenes with bromine
Alkenes react with bromine in an addition reaction, where the double bond breaks and a bromine atom attaches to each carbon, forming a dibromoalkane
48
How can bromine water be used to distinguish between an alkane and an alkene?
Bromine water is decolorized by alkenes, due to their double bond reacting with bromine. Alkanes, however, do not react and the bromine water stays orange/brown