Principles of Chemistry Flashcards

(55 cards)

1
Q

Define atom

A

the smallest particle of an element that can exist and still retain the properties of that element

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2
Q

Define molecule

A

a group of two or more atoms bonded together

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3
Q

What 3 subatomic particles make up the atom

A

Proton
Neutron
Electron

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4
Q

What is the nucleus of an atom

A

the small, dense centre of an atom that contains protons and neutrons

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5
Q

What is the atomic number (chem)

A

The number of protons in an atom

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6
Q

What is the mass number (chem)

A

The total number of protons and neutrons in an atom

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7
Q

What is an isotope

A

Isotopes are different atomic forms of the same element which have the same number of protons but different numbers of neutrons

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8
Q

What is relative atomic mass (Aᵣ)

A

The weighted average mass of the isotopes of an element compared to 1/12 the mass of a carbon-12 atom

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9
Q

How are elements arranged in the periodic table

A

Order of atomic number
Groups/Periods

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10
Q

Do metals conduct electricity?

A

Yes
Delocalised electrons

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11
Q

Do non-metals conduct electricity?

A

No
Lack free electrons (apart from graphite)

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12
Q

What type of oxides do metals form?

A

Basic oxides

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13
Q

What type of oxides do non-metals form?

A

Acidic oxides

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14
Q

Covalent bonding definition

A

Strong electrostatic forces of attraction between common nuclei and a shared pair of electrons

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15
Q

Why do substances with simple molecular structures have low melting and boiling points?

A

Intermolecular forces between molecules are weak
Little energy to overcome

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16
Q

Intermolecular forces in simple molecular structures increase as what increases?

A

Mᵣ
Relative molecular mass

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17
Q

What state are most molecular substances at RTP?

A

Liquid/Gas

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18
Q

Why do intermolecular forces in simple molecular structures increase with Mᵣ?

A

As Mᵣ increases
Molecules are larger
Surface area increases
More points of contact between molecules

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19
Q

Why do substances with giant covalent structures have high melting/boiling points?

A

It requires lots of energy to break the strong covalent bonds between atoms

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20
Q

Describe the structure of diamond

A

Each carbon atom forms 4 covalent bonds

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21
Q

Why is diamond so hard

A

The strong covalent bonds hold the atoms in a very rigid lattice structure

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22
Q

Why doesn’t diamond conduct electricity?

A

No free electrons/ions

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23
Q

Describe the structure of graphite

A

Each carbon atom forms 3 covalent bonds
Layers of carbon atoms held together weakly by intermolecular forces
Layers are free to slide over each other

24
Q

Why does graphite conduct electricity?

A

Each carbon atom has 1 delocalised electron

25
Are giant covalent structures soluble in water?
No
26
Describe the structure of C₆₀ Fullerene
Hollow spheres made up of 60 carbon atoms
27
Is C₆₀ Fullerene giant covalent?
No
28
Why is C₆₀ Fullerene soft?
C₆₀ molecules are only held together by intermolecular forces so they can slide over each other
29
Why is C₆₀ Fullerene a poor conductor of electricity?
Each carbon atom in C₆₀ has 1 delocalised electron but they can't move between molecules
30
Do covalent compounds usually conduct electricity?
No
31
Definition of ionic bonding
Strong electrostatic forces of attraction between 2 oppositely charged ions
32
Define ion
An electrically charged atom or group of atoms by the loss/gain of electrons
33
What is a cation
Positive ion
34
What is an anion
Negative ion
35
What type of ions do metals form
Cation
36
What type of ions do non-metals form?
Anion
37
Why do compounds with giant ionic lattices have high melting/boiling points?
The strong electrostatic forces between oppositely charged ions in the giant lattice require a lot of energy to overcome and break apart
38
Can ionic compounds conduct electricity when solid?
No
39
When can ionic compounds conduct electricity and why?
Molten/Dissolved The ions are free to move and carry charge
40
What is metallic bonding?
The strong electrostatic forces of attraction between positive metal ions and the sea of delocalised electrons
41
What is a valence electron
The electrons in the outer shell of an atom
42
Why do metals have high melting/boiling points?
Many strong metallic bonds in giant metallic structures Lots of energy required to overcome
43
Why do metals conduct electricity?
Free electrons are able to move and carry charge
44
Why are metals malleable and ductile
Layers of positive ions can slide over one another (regular structure) Bonding is not disrupted
45
Why do metals conduct heat?
Delocalised electrons transfer heat energy Ions in the lattice vibrate in place, passing energy to neighbouring ions
46
What is an alloy?
An alloy is a mixture of two or more elements, with at least one metal
47
Why are most alloys harder than pure metals?
Regular lattice disrupted by different sized atoms Harder for layers to slide
48
What is a mole (mol)
A mole is a unit used to measure the amount of substance. It represents 6.02 × 10²³ particles
49
What is empirical formula?
The empirical formula is the simplest whole number ratio of atoms of each element in a compound
50
What is molecular formula?
The molecular formula shows the actual number of atoms of each element in a molecule
51
What is the formula n = c × V used for?
It’s used to calculate the number of moles (n) of a solute in a solution c is concentration (mol/dm³) V is volume (dm³)
52
Mass = ? (chemistry moles calcs)
m = Mᵣ × Moles
53
Percentage yield = ?
actual yield / theoretical yield
54
v = ? (At RTP) (Chem)
v = 24n
55
How do you convert between dm³ and cm³
1 dm³ = 1000 cm³