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Organic Chemistry Flashcards

(64 cards)

1
Q

What is organic chemistry?

A

The study of carbon-based compounds and their reactions.

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2
Q

What are hydrocarbons?

A

Compounds made of only carbon and hydrogen

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3
Q

What are functional groups?

A

Specific atom arrangements that define chemical properties, like hydroxyl (-OH) and carboxyl (-COOH).

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4
Q

What is the difference between alkanes, alkenes and alkynes?

A

Alkanes have single bonds, alkenes have double bonds, and alkynes have triple bonds.

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5
Q

What is isomerism?

A

Molecules with the same formula but different structures.

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6
Q

What is a polymer?

A

Large molecules made of repeating smaller units (monomers).

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7
Q

What is the role of catalysts in organic reactions?

A

They speed up reactions without being consumed.

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8
Q

What are aromatic compounds?

A

Molecules with conjugated ring structures, like benzene.

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9
Q

What is an electrophile?

A

A species that accepts electrons in a reaction.

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10
Q

What is esterification?

A

A reaction between an alcohol and an acid to form an ester.

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11
Q

What is an alkyl group?

A

A hydrocarbon chain attached to a molecule.

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12
Q

What are alcohols?

A

Organic compounds containing an -OH (hydroxyl) group.

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13
Q

What is the difference between ketones and aldehydes?

A

Aldehydes have a carbonyl group at the end of a chain, while ketones have it in the middle.

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14
Q

What are carboxylic acids?

A

Organic acids with a -COOH functional group.

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15
Q

What is a nucleophile?

A

A species that donates electrons in a reaction.

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16
Q

What is a condensation reaction?

A

A reaction where two molecules combine, releasing water.

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17
Q

What is cracking in organic chemistry?

A

Breaking down large hydrocarbons into smaller ones.

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18
Q

What are amines?

A

Organic compounds containing nitrogen (-NH₂ group).

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19
Q

How do esters smell?

A

They often have fruity or sweet aromas.

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20
Q

What is the difference between addition and substitution reactions?

A

Addition reactions add atoms to a molecule, while substitution replaces one atom with another.

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21
Q

What is the hybridization of the carbon atom in methane (CH₄)?

A

\sp^3 \ hybridization.

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22
Q

Why are ethers less reactive than alcohols?

A

Ethers lack the reactive hydroxyl (-OH) group.

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23
Q

What is the IUPAC name for acetone?

A

Propanone

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24
Q

How does the presence of a nitro group affect the reactivity of benzene?

A

It deactivates benzene, making it less reactive in electrophilic substitution.

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25
What is the functional group in amides?
\-CONH_2 \.
26
Why are alkyl halides used in nucleophilic substitution reactions?
The halogen atom is a good leaving group.
27
What is Markovnikov's rule in addition reactions?
The hydrogen atom adds to the carbon with more hydrogens, and the other group adds to the carbon with fewer hydrogens.
28
What is the product of the oxidation of a primary alcohol?
An aldehyde, and further oxidation produces a carboxylic acid.
29
Why are aromatic compounds unusually stable?
They have delocalized \\\pi \-electrons forming a resonance structure.
30
What is the difference between cis and trans isomers?
Cis isomers have groups on the same side; trans isomers have groups on opposite sides.
31
What is the role of Grignard reagents in organic synthesis?
They act as nucleophiles to form carbon-carbon bonds.
32
What is the functional group in thiols?
\-SH \.
33
How does the inductive effect influence acidity in organic compounds?
Electron-withdrawing groups increase acidity by stabilizing the conjugate base.
34
What is the product of the reaction between an acid chloride and an alcohol?
An ester
35
Why are alkynes more acidic than alkenes and alkanes?
The \sp \ hybridized carbon in alkynes holds electrons closer, stabilizing the conjugate base.
36
What is the product of the reaction between a ketone and hydrogen cyanide (HCN)?
A cyanohydrin.
37
Why are phenols more acidic than alcohols?
The phenoxide ion is stabilized by resonance in phenols.
38
What is the functional group in aldehydes?
\-CHO \.
39
How does the presence of a double bond affect the geometry of alkenes?
Alkenes have a planar geometry around the double bond due to \sp^2 \ hybridization.
40
What is Hybridization?
Hybridization is the mixing of atomic orbitals to form new hybrid orbitals, which determines molecular shape and bonding properties.
41
Why is using a hot plate with a loose-fitting cover safer than using a Bunsen burner to heat organic liquids when measuring their boiling points?
A hot plate is safer than a Bunsen burner because it reduces the risk of fire when heating flammable organic liquids and provides better temperature control.
42
What is crude oil, and how is it formed?
Crude oil is a fossil fuel formed from ancient organic matter buried and subjected to heat and pressure over millions of years.
43
What are the main components of crude oil?
Mostly hydrocarbons, with small amounts of sulfur, nitrogen, and oxygen compounds.
44
How does fractional distillation separate crude oil into different products?
It heats crude oil, separating components based on boiling points into fuels like petrol, diesel, and kerosene.
45
What are some common fuels derived from crude oil, and how are they used?
Petrol (cars), diesel (trucks), kerosene (jet fuel), and LPG (cooking, heating).
46
What environmental concerns are associated with crude oil extraction and use?
Air pollution, greenhouse gas emissions, oil spills, and habitat destruction.
47
How do oil spills impact marine ecosystems, and what cleanup methods exist?
They harm wildlife and ecosystems; cleanup methods include skimming, dispersants, and bioremediation.
48
What is the difference between conventional and unconventional crude oil sources?
Conventional oil is easily extracted; unconventional (shale oil, tar sands) requires specialized techniques.
49
How does crude oil refining work, and what products are obtained from it?
Refining separates and chemically processes crude oil into fuels, lubricants, and petrochemicals.
50
What role does OPEC play in the global crude oil market?
OPEC regulates oil production among member countries to influence prices and supply.
51
What alternatives to crude oil are being developed to reduce dependence on fossil fuels?
Renewable energy sources like solar, wind, biofuels, and hydrogen fuel.
52
What is the molecular formula of butane?
C₄H₁₀
53
How does the structural formula of propane differ from butane?
Propane has three carbon atoms (C₃H₈), while butane has four (C₄H₁₀).
54
What is the molecular formula of methane?
CH₄
55
What is the molecular formula of ethane?
C₂H₆
56
How does the number of carbon atoms affect boiling points of methane, ethane, propane, and butane?
More carbon atoms increase the boiling point (methane < ethane < propane < butane).
57
Why are methane, ethane, propane, and butane considered alkanes?
They only contain single bonds and follow the CₙH₂ₙ₊₂ formula.
58
What is the primary use of methane and ethane?
Methane is used in natural gas for heating, ethane is a feedstock for plastics.
59
Why is propane stored as a liquid in gas cylinders?
It liquefies under moderate pressure, making transport and storage easier.
60
What are the products of complete combustion of methane, ethane, propane, and butane?
Carbon dioxide (CO₂) and water (H₂O).
61
Which alkane is most commonly used in lighters?
Butane, due to its liquid state at room temperature.
62
How do methane and ethane contribute to greenhouse gases?
Methane is a potent greenhouse gas, ethane contributes to air pollution when leaked.
63
What common fuels are derived from propane and butane?
LPG (Liquefied Petroleum Gas), used for heating and cooking.
64
Describe and explain how crude oil is separated into fractions by fractional distillation?
Crude oil is heated, vaporized, and enters a fractionating column. Larger hydrocarbons condense lower, smaller ones rise higher. Fractions like bitumen, diesel, kerosene, petrol, and gases are collected by boiling points.