organic chemistry Flashcards

(35 cards)

1
Q

give stages 1-2 of the crude oil timeline?

A

1.millions of years ago,there were many tiny animals and plants in the sea
2.when they died they fell to the bottom of the sea

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2
Q

give stages 3-4 of the crude oil timeline?

A

3.at the bottom of the sea they were covered in mud
4.overtime layers of rock built up on top of the dead organisms

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3
Q

give stages 5-6 of the crude oil timeline?

A

5.the rock put dead organisms in hot, high pressure,low oxygen conditions
6.these conditions over millions of years formed crude oil

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4
Q

what is crude oil?

A

crude oil is a hydrocarbon that is a mixture of alkanes

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5
Q

what are hydrocarbons?

A

hydrocarbons are compounds that contain only hydrogen and carbon

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6
Q

what is fractional distillation?

A

is a method used to separate mixtures of liquids with similar boiling points

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7
Q

describe the process for fractional distillation?(4 steps)

A

1.crude oil is heated,vapourised and enters at the bottom of the column
2.the vapour rises up the column which is hottest at the bottom and coolest at the top
3.the different liquids in the vapour will condense at their boiling points
4.fractions are then collected,these are mixtures over a small range of boiling point temperatures

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8
Q

why is carbon a useful element for making large compounds?

A

each atom of carbon can form 4 strong bonds (covalent)

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9
Q

what are alkanes?

A

alkanes are saturated compounds-every carbon atom has full single covalent bonds-no double bonds-hydrocarbons

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10
Q

how can we describe the alkane series?

A

as a homologous series-they have similar properties and react in a similar way

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11
Q

what is the general formula for alkanes?

A

CnH2n+2

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12
Q

name four alkanes?

A

methane
ethane
propane
butane

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13
Q

give the molecular formula for methane

A

CH4

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14
Q

give the molecular formula for ethane

A

C2H6

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15
Q

give the molecular formula for propane

A

C3H8

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16
Q

give the molecular formula for butane

17
Q

what is an alkene?

A

an alkene is an unsaturated type of hydrocarbon containing at least one double bond between carbon atoms

18
Q

state 2 differences between alkenes and alkanes?

A

1.alkenes are unsaturated hydrocarbons which contain at least one double bond between carbon atoms whereas alkanes are a saturated hydrocarbon which contains only single bonds between carbon atoms
2.the double bond in alkenes makes them more reactive than alkanes

19
Q

how do we test for alkenes?

A

to test for alkenes we use bromine water which is orange-if we shake our alkene with bromine water then the bromine water will turn colourless

20
Q

what is the key rule for balancing cracking equations?

A

the number of hydrogen and carbon atoms must be the same on both sides of the reaction

21
Q

explain the trend of boiling points in hydrocarbons?

A

as the length of the hydrocarbon chain increases the boiling point also increases
this is because longer chains have more intermolecular forces between them requiring more energy to overcome

22
Q

explain the trend of viscosity in hydrocarbons?

A

viscosity (how easily a substance flows) also increases as the length of the hydrocarbon chain increases due to more stronger intermolecular forces between carbon atoms making them less fluid and more viscous

23
Q

explain the trend of flammability in hydrocarbons?

A

flammability decreases as the chain length increases
this is because shorter chains are more volatile and ignite more easily whereas longer chains require more energy to vaporise and burn

24
Q

what is cracking?

A

cracking is a chemical process where useless long chain alkanes are cracked/broken down to produce more useful short chain alkanes and alkenes

25
why do we use cracking?
because long chain hydrocarbons do not make good fuels-not very flammable which is a problem due to high demand for short chain hydrocarbons to used as fuels.
26
what two ways can we crack hydrocarbons?
catalytic cracking steam cracking
27
what conditions are required for catalytic cracking?
-high temperature and a catalyst(usually a transition metal)
28
what conditions are required for steam cracking?
high temperature,high pressure and steam
29
what can alkenes be used to make?
polymers
30
what is complete combustion?
when a fuel is burnt in a good supply of oxygen-carbon dioxide and water are always the products
31
what is incomplete combustion?
fuels burnt in a limited supply of oxygen carbon monoxide is always produced
32
what is a polymer?
a large molecule made up of many small repeating units called monomers which are alkene molecules
33
describe the structure and bonding of a polymer?
-each polymer molecule is made up of smaller units called monomers -very large molecules-the atoms in a polymer molecule are joined together by strong covalent bonds in long chains -only have single covalent bonds
34
explain the properties of polymers? melting point
-high melting point-intermolecular forces between polymer molecules are strong compared to intermolecular forces between small molecules-require lots of energy to overcome
35
explain the properties of polymers? solid at room temp
intermolecular forces of attraction between polymer molecules are relatively strong-in order to melt a polymer we have to break these intermolecular forces-takes a lot of energy-solid at room temp-high melting point