Organic chemistry reactions Flashcards

(66 cards)

1
Q

how many free radical substitutions to know

A

1

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2
Q

how many ionic addition reactions to know

A

5

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3
Q

example of free radical substitution reaction

A

CH4 + Cl2 -> CH3Cl + HCl

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4
Q

CH4 + Cl2 -> CH3Cl + HCl

reagent

A

chlorine

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5
Q

CH4 + Cl2 -> CH3Cl + HCl

condition

A

u.v light

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6
Q

what undergoes free radical substitutions

A

alkanes

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7
Q

what undergoes ionic addition reactions

A

alkenes

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8
Q

what type of ionic addition reaction is this

C2H4 + H2 -> C2H6

A

hydrogenation

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9
Q

reagent: C2H4 + H2 -> C2H6

A

hydrogen

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10
Q

condition: C2H4 + H2 -> C2H6

A

Ni catalyst and 200º C

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11
Q

what is this: C2H4 + Br2 -> C2H4Br2

A

addition of bromine: test for unsaturation

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12
Q

reagent: C2H4 + Br2 -> C2H4Br2

A

bromine

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13
Q

condition: C2H4 + Br2 -> C2H4Br2

A

none

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14
Q

function of this: C2H4 + Cl2 -> C2H4Cl

A

1st stage in synthesis of PVC from ethene

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15
Q

reagent: C2H4 + Cl2 -> C2H4Cl

A

chlorine

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16
Q

condition: C2H4 + Cl2 -> C2H4Cl

A

none

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17
Q

what type of reaction is this? C2H4 + HCl -> C2H5Cl

A

ionic addition reaction

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18
Q

reagent: C2H4 + HCl -> C2H5Cl

A

hydrogen chloride

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19
Q

reagent: C2H4 + H2O -> C2H5OH

A

water

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20
Q

condition: C2H4 + H2O -> C2H5OH

A

none

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21
Q

what type of reaction is a dehydration reaction

A

elimination reaction

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22
Q

dehydration reaction example

A

C2H5OH -> C2H4 + H2O

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23
Q

condition: C2H5OH -> C2H4 + H2O

A

Al2O3 + heat

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24
Q

function of this elimination reaction: C2H4Cl2 -> C2H3Cl + HCl

A

2nd stage in synthesis of PVC from ethene

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25
C2H3Cl 2 names
chloroethene | vinyl chloride
26
oxidation of primary alcohols to
aldehydes
27
reagents: C2H5OH -> CH3CHO
sodium dichromate (VI), sulphuric acid, water
28
conditions: C2H5OH -> CH3CHO
heat, antidumping granules
29
apparatus: C2H5OH -> CH3CHO
distillation
30
reagents: C2H5OH -> CH3COOH
sodium dichromate (VI), sulphuric acid, water
31
conditions: C2H5OH -> CH3COOH
heat, antibumping granules
32
apparatus: C2H5OH -> CH3COOH
reflux
33
secondary alcohol oxidised to
ketone
34
propan-2-ol oxidised to
propanone
35
propan-2-ol molecular formula
CH3CH(OH)CH3
36
propane formula
CH3COCH3
37
reagents: CH3CH(OH)CH3 -> CH3COCH3
sodium dichromate (VI), sulphuric acid, water
38
conditions: CH3CH(OH)CH3 -> CH3COCH3
heat, antibumping granules
39
one example of a type of condensation reaction
esterification reaction
40
esterification reaction general
carboxylic acid + alcohol ester + water
41
example of condensation reaction
CH3COOH + C2H5OH -> CH3COOC2H5 + H2O
42
condition:CH3COOH + C2H5OH -> CH3COOC2H5 + H2O
heat | concentrated sulphuric acid
43
function of concentrated sulphuric acid
catalyst | dehydrating agent to favour the forward reaction
44
what is produced when you react alcohol as an acid with sodium metal
salt and hydrogen gas
45
what is produced when you reaction ethanol with sodium
sodium ethoxide and hydrogen gas
46
sodium ethoxide
C2H5ONa
47
reduction of a carboxylic acid x2
aldehyde and then primary alcohol
48
reagent for reduction reactions
hydrogen
49
catalyst for reduction reactions
nickel
50
equation for reduction of ethaonic acid x2
CH3COOH + H2 -> CH3CHO -> C2H5OH
51
equation for reduction of propanone
CH3COCH3 + H2 -> CH3CH(OH)CH3
52
carboxylic acid + metal ->
salt + hydrogen gas
53
carboxylic acid + metal carbonate ->
salt + water + carbon dioxide
54
reacting ethanoic acid with any type of metal, what do you get
... ethanoate
55
what are aldehydes compared to all other homologous series?
great reducing agents
56
condition for all aldehyde tests
heat
57
aldehyde + acidified potassium manganate (VII)
CH3CHO + Mn (+7) -> CH3COOH + Mn (+2)
58
aldehyde + fehling's solution
CH3CHO + Cu(+2) -> CH3COOH + Cu(+1)
59
aldehyde + tollen's reagent
CH3CHO + Ag(+1) -> CH3COOH + Ag(0)
60
what are all of these aldehyde + acidified potassium manganate (VII) aldehyde + fehling's solution aldehyde + tollen's reagent
diagnostic tests to show the presence of an aldehyde
61
PVC
polychloroethene
62
polystyrene
polophenylethene
63
base hydrolysis of an ester is called
saponification reaction
64
ester + base ->
alcohol + salt of carboxylic acid
65
salt of carboxylic acid
soap
66
example of saponification reaction
Glycerol tristerate + NaOH -> Glycerol + sodium sterate