Oxidation, Reduction and Redox Flashcards

1
Q

Redox

A

A reaction where one substance loses electrons and is oxidised, while another substance gains electrons and is reduced

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1
Q

Oxidation number

A

Number assigned to an atom in a substance and represents the number of electrons lost or gained by an atom of an element

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2
Q

What is the oxidation number of an element

A

0

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3
Q

What happens to the oxidation number during oxidation

A

Oxidation number increases

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4
Q

What happens to the oxidation number during reduction

A

Oxidation number goes down

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5
Q

Oxidising agent

A

A substance that oxidises another substance by removing electrons from it. (It is also the substance which is reduced)

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6
Q

Reducing agent

A

A substance that reduces another substance by donating electrons to it. ( it is also the substance which is oxidised)

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7
Q

Half equation for the reduction of H+ ions

A

2H20 + 2e ——–> 2OH- + H2

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8
Q

How to do half equations for oxidation

A

x ——-> y + e

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9
Q

How to do half equations for reduction

A

x + e- ——–> y

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10
Q

How do you combine half equations to form the overall reactions

A
  1. Find out which equation is reduction and which is **oxidation **
  2. Re-write the equations, balancing them and adding the e- accordingly to balance the charges
  3. Get the same number of electrons in both equations by multiplying one or both of the equations
  4. Cancel out the extra ions/substances.
  5. Things on the left can only cancel out with things on the right
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11
Q

Half equation for the reduction of MnO4

A

MnO4- + 8H+ 5e- ———> Mn2+ + 4H20

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12
Q

What is the colour of MnO4 / manganate ion

A

Purple

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13
Q

What is the half equation for the reduction of Cr2O7

A

Cr2O7 2- + 14H+ + 6e- ——–> Cr 3+ + 7H2O

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14
Q

Colour of Cr2O7 2- ion

A

Orange

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15
Q

Colour of Cr 3+ ion

A

Green

16
Q

Half equation for oxidation of S2O3 2-

A

2S2O3 2- ——-> S4O6 2- + 2e-

17
Q

Disproportionation reaction

A

A reaction in which an element is both oxidised and reduced in the same reaction

18
Q

How do you know if one ion/element is a better oxidising or reducing agent

A

The higher the increase/decrease in oxidation number, the better/stronger it is.

If change in oxidation number is the same, compare the electronegativities.
Better oxidising agent = Higher electronegativity
Better reducing agent = Lower electronegativity

19
Q
A