Paper 1: BCS, CP Flashcards
Describe denture base material
PMMA powder + MMA liquid
- PMMA = MMA pre-polymerised into powder via suspension polymerisation
- acts as filler as doesn’t polymerise more
Powder + Liquid HC using Dough Technique
Advantages of using HC Dough Technique
Using MMA alone: vol. shrinkage 21% (7% linear shrinkage)
- 2/3 replace w/ PMMA vol. shrinkage 7% (~2% linear)
Exotherm red.
Discuss composition of denture base PMMA
Powder
- PMMA spherical beads 10-200mmetre
- benzoyl peroxide (0.2-0.5%); initiator
- pigments (1-2%)
- Ti/Zn oxides; opacifiers
Liquid
- MMA
— volatile, flammable
— store dark glass bottle; avoid spontaneous polymerisation = extend shelf life
- ethylene glycol dimethacrylate (10%); cross-linking monomer
— form covalent bonds b/w PMMA chains
— improve craze resistance
— too much = brittle
- hydroquinone (0.0006%); inhibitor
— react w/ FRs that form in bottle
— form stabilised FRs; can’t initiate polymerisation
Activation requirements for HC polymerisation
Initiator (benzoyl peroxide) + heat (~80)
Discuss stages of HC polymerisation of PMMA
PMMA + MMA mixed -> Dough formed which is heated (80)
FR polymerisation occurs forms cured plastic polymer
Initiation: FR attack MMA double bond
Propagation: (chain growth); MMA monomers add to chain
Termination: 2 growing chains meet; FRs combine form stable covalent bond
Discuss the formation of crazes in denture bases
Internal strains due to thermal contraction
- minimise: use acrylic teeth, allow flask to cool slowly
Relieving produce tiny defects (crazes)
- form cracks which grow = #
Form in response to;
- heat; polishing
- differential thermal contraction around porcelain teeth
- attack by solvents; pt drinking alcohol
Discuss the formation of porosities in denture bases and why this is problematic
Exothermic: if over BPt (MMA 100.3)
Gaseous: incorrect curing; monomer vaporises leading voids
Contraction: flasks not kept under Constant Spring pressure during curing cycle
Granular: incorrect mixing/packing; structural deficiency due to loss of monomer
Problem
- H2O fills voids
- unreacted monomer (toxic) leach out
- further voids -> more H2O absorbed
- leads to crazes + failure
Advantages of HC PMMA denture base
Glass transition temp: 105/125 (high)
- well above temp. encountered in use
— polishing, cleaning
Specific gravity: low; doesn’t fall out
Aesthetic
Manufacture + repair easy
Good longevity: 5-10yr
Disadvantages of HC PMMA denture base
Toxicity: residual monomer (0.5%)
- contact dermatitis, mucosal irritation
Elastic modulus: 2.6GPa (low)
Impact strength: low (cracks grow), brittle
Fatigue strength: low; major cause failure
Abrasion resistance: low
Thermal conductivity/diffusivity: low; is insulator
- potentially scald as don’t feel temp.
Dimensional stability: polymerisation shrinkage
Discuss rubber reinforcement of HC acrylics
Butadiene styrene
- introduce rubber phase
- high impact acrylics
- cracks stop growing when rubber domains reached
- high degree of resistance to #
- lower flexural modulus; long term fatigue failure due to excessive flexure
Discuss potential fibre reinforcements of HC acrylics
Carbon: difficult handling, poor aesthetic
Polyaramid plain fabric (Kevlar)
- ineffective: poor bonding b/w resin and fibres
Ultra-high MWt polyethylene (UHMPE)
- neutral colour
- biocompatible
- low density
- surface treated for bonding to resin
- fabrication T consuming
Glass: most promise
- hydrophilic glass + hydrophobic PMMA problematic
- incorporated in resin as short fibres; in cloth or loose form
Explain why HC PMMA dentures need to be kept in H2O
In storage/mouth absorbs ~2% H2O
If drys out will absorb >2% H2O
If this continues crazes form
- due to relieving IS + residual monomer leaching
- crazes -> cracks -> fail; red. longevity
Uses for RT PMMA
Denture repair Relining denture bases Additions to denture Special trays Temp. crown and bridge
How is RT cured acrylic mixed?
RT PMMA (pre-polymerised MMA) powder + RT MMA monomer liquid mixed in Dough Technique
Composition of RT cured PMMA
Powder
- PMMA; finer particle size cf HC
- BP; initiator
- colour pigments
- Ti/Zn oxides; opacifiers
Liquid
- MMA monomer
- hydroquinone; inhibitor
- N,N-dimethyl-p-toluidine (DMPT); activator
Describe the RT polymerisation process of RT PMMA
Liquid + powder mixed
PMMA beads dissolve in MMA liquid
Activation: DMPT breakdowns BP liberating FRs
FRs attack MMA double bonds
- follows initiation, propagation + termination stages
~10min cure
How does the finer particle size of RT PMMA powder affect the curing process?
More rapid diffusion of MMA into PMMA beads
- rapidly gelates to hard mass
Advantages of RT PMMA cf HC PMMA
Cheaper
Less technician T; don’t have to send to lab
Chair side use
Disadvantages of RT PMMA cf HC PMMA
Physically weaker
- low MWt PMMA affect mechanical properties
- > residual monomer (3-5%) (not all able to polymerise)
— leaches -> porosities
Aesthetics: poor stability; DHPT causes yellowing
Tg: lower (70-80)
Porosity
- more rapid gelation
- hand mixing incorporate air
Inc. H2O uptake
- low MWt
- loss of residual monomer
- porosity
Discuss PEMA; what it is, monomers it can be mixed with, Tg
Higher methacrylate (cf PMMA) powder mixed w/ (usually) higher MWt monomers using Dough Technique
Monomers
- can’t use MMA = incoherently mixed product
- none = tissue conditioner
- higher MWt monomers (ethyl, butyl, hexyl)
Tg: 65 (
Uses of RT PEMA acrylics
Tissue conditioner (no monomer) Hard reliner Soft lining material Extension of special trays and dentures Temp. crown + bridge
Discuss PEMA tissue conditioners
PEMA mixed w/ no monomer
- no polymerisation occurs
- forms viscoelastic gel via polymer chain entanglement
- short life (3d); no polymerisation, alcohol volatile, plasticiser leaching
Uses
- denture lining; allow tissues to recover
- maxillofacial prosthesis; obturators
- functional impression materials
What is the function of PEMA powder in PEMA/EMA?
Same as PMMA
Acts as virtual filler
- dec. shrinkage
- lower exotherm
What is the purpose of soft lining materials?
Make denture more comfortable for pt in area has traumatised soft tissues