perodic classification Flashcards

1
Q

s block electronic config

A

ns^1-2

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2
Q

group 1 elements are known as

A

alkali elements

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3
Q

group 2 are knows as

A

alkaline earth elements

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4
Q

p-block config

A

ns^2np^1-6

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5
Q

elements who show diagonal relationship

A

li with mg , be with al, b with si

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6
Q

d-block config

A

(n-1)d^1-10ns^0-2

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7
Q

IONIC radius

A

ionic radii>neutral atom , radii directly propotional negative charge,

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8
Q

what is ionization enthalpy

A

enegry required to remove an outermost electron from an ground atom to form cation

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9
Q

trend in ionization enthalpy

A

IE increases left to right and decreases down the group,but half & fully filled orbitals are more stable ho high IE, IE inversly to atomic size ,charge directly to IE,
IE1 of group 2 element > of grp 13

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10
Q

what is electron enthalpy

A

energy released when an electron is added to an atom

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11
Q

trend in electron gain enthalpy

A

EGE increses left to right, and decreases down the group, it is inversly to atomic size , directly to nuclear charge , half and fully filled EGE will be less

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12
Q

what is electronegativity

A

tendecy of an atom to attaract shared pair of electron towards itself, only depend upon nuclear charge or size

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13
Q

trend in electonegativity

A

left to right increases, down the group decreases

flourine is the most electronegative element

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14
Q

metallic character

A

will decrease from left to right

increases down the group

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15
Q

chemical reactivity for metals

A

invesely to IE,EN directly to atomic radii

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16
Q

reactivity for non-metals

A

directly to EN,ege and inversely to atomic radii

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17
Q

trend of chemical reactivity

A

down the group ,metals reactivity increases and non metal decreases , across the group metals reactivity decreases, non metal increases

18
Q

reducing character

A

increase down the group,decrease across period

19
Q

oxidizing character

A

decrease down the group, increases across the priod

20
Q

oxides

A

M+02—->MxOy

21
Q

non-metals

A
Hydrogen (sometimes)
Carbon.
Nitrogen.
Oxygen.
Phosphorus.
Sulfur.
Selenium.
Fluorine
bromine 
iodine
22
Q

acidic

A

the oxide which form acid on hydrolysis

usually non-metals oxides are acidic in nature

23
Q

basic

A

the oxide which form base on hydrolysis

usually metal oxides form base

24
Q

amphoteric

A

the oxide which doesn’t react with H2O but can react with both acid and base
eg:Al203

25
Q

neutral

A

this oxide doesn’t react with anything
C0(carbon monooxide)
NO(nitric acid)

26
Q

ionization potential

A

it is the minimum amount of energy required to remove an outermost loosely held electron from isolated gaseous atom

27
Q

successive IP

A

when any element remove more than 1 electron , nucleus increases charge to hold remaining electron
so the successive IP gets exceptionally high

successive IP∝ energy required
no of electron ∝ 1/z-eff

28
Q

most stable electron configuration

A

ns^2np^6–> noble gas config.

29
Q

factors affecting IP

1. atomic size or atomic radii

A
down the group ∝ no of shell increases 
IP∝1/no. of shell 
IP DECREASES DOWN THE GROUP
across the period ∝no of electron 
electron increases ∝1/size 
IP INCREASES ACROSS THE PERIOD
30
Q

factors affecting IP

nuclear charge

A

down the group ∝ 1/nuclear charge

across the period ∝ nuclear charge

31
Q

factors affecting IP

penetration power

A

highest penetration power or IP required to remove electron is s>p>d>f

32
Q

factors affecting IP

electronic configuration

A

half-filled and fully filled orbital are exceptionally stable. Due to symmetric distribution

33
Q

exception of IP

A

shielding and screening effect

IP of 4th period > IP of 3rd period

34
Q

electron gain enthalpy

A

it is the minimum amount of energy required or released when an electron is added
negative means energy is released
positive means energy is absorbed
this concept of electron gain is mostly applicable for non metals bcoz they have a tendency to accept electrons

35
Q

second electron gain

A

it is always positive ,because repulsion increases after 1st electron

36
Q

factors affecting electron gain enthalpy

atomic size

A

down the group electron gain enthalpy decreases
across the periods increases
halogens have the highest value of electron gain enthalpy

37
Q

electropositivity

A

tendency to lose electron and attain positive ion
a more electropositive character means more metallic character
ACROSS THE PERIOD DECREASES
DOWN THE GROUP INCREASES

38
Q

analomous behavior

A
every 1st element of the every group is different from rest of the group 
smallest size 
highest IP 
highest value of EGE
highest electronegativity
39
Q

alkali metals

A

most reactive ,strongest reducing agent and have lowest IP

40
Q

halogens

A

most reactive ,strongest oxidizing agent anf have high IP

41
Q

Size of species

A

Size of species inversely proportional to nuclear charge

42
Q

Exception in electron gain enthalpy

A

In group 17 , cl > F because of F small size