Phase Changes Flashcards

1
Q

The properties of a phase are determined by the balance of what?

A

The potential and kinetic energy of particles

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2
Q

What two forces determine the potential energy of a sample of matter?

A

Intramolecular and intermolecular forces

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3
Q

Among solids, liquids, and gases, which has the strongest intermolecular forces?

A

Solids

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4
Q

The temperature and kinetic energy of particles rises in an endothermic or exothermic phase change?

A

Endothermic

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5
Q

In an endothermic phase change, do intermolecular forces become stronger or weaker?

A

Weaker

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6
Q

The temperature and kinetic energy of particles decreases in an endothermic or exothermic phase change?

A

Exothermic

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7
Q

In an exothermic phase change, do intermolecular forces become stronger or weaker?

A

Stronger

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8
Q

What is vaporization?

A

Liquid to gas

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9
Q

What is sublimation?

A

Solid to gas

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10
Q

What phase change is fusion?

A

Melting (solid to liquid)

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11
Q

What is deposition?

A

Gas to solid

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12
Q

Is melting/fusion exothermic or endothermic?

A

Endothermic

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13
Q

Is deposition exothermic or endothermic?

A

Exothermic

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14
Q

Is vaporization exothermic or endothermic?

A

Endothermic

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15
Q

Is sublimation exothermic or endothermic?

A

Endothermic

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16
Q

Is freezing exothermic or endothermic?

A

Exothermic

17
Q

Is condensation exothermic or endothermic?

A

Exothermic

18
Q

-ΔH fus is the enthalpy change of which phase change?

A

Freezing (opposite of melting/fusion)

19
Q

-ΔH vap is the enthalpy change of which phase change?

A

Condensation (opposite of vaporization)

20
Q

-ΔH subl is the enthalpy change of which phase change?

A

Deposition (opposite of sublimation)

21
Q

Does it take more energy to melt a solid or vaporize a liquid?

A

Vaporize a liquid because more energy is required to completely separate molecules to make a gas.

22
Q

Within a phase, increasing heat does what?

A

Increases temperature

23
Q

At melting and boiling points, what does heat added to a system do?

A

It goes to overcoming intermolecular forces

24
Q

At melting and boiling points, does heat added to a system change the temperature?

A

No, the temperature remains constant until the intermolecular forces are broken

25
Q

What formula represents the energy associated with heating within a phase?

A

q = mcΔT

26
Q

What formula represents the energy associated with a phase change?

A

q = (ΔH phase change)(moles)

27
Q

How do you calculate the total energy of a phase change?

A

Add the energies of each step

28
Q

On a phase diagram, what is a fusion curve?

A

The line between solid and liquid

29
Q

On a phase diagram, what is a vaporization curve?

A

The line between liquid and gas

30
Q

On a phase diagram, what is a sublimation curve?

A

The line between gas and solid

31
Q

What is a supercritical fluid?

A

A substance at a temperature and pressure above the critical point where distinct liquid and gas phases do not exist.

32
Q

Why does the fusion curve for water have a negative slope?

A

Ice is less dense than liquid water

33
Q

When a given pressure and temperature fall on the vaporization curve of a phase diagram, what two things are in equilibrium?

A

The liquid and gas phases