Physics Flashcards
What are p-block elements?
Elements where the differentiating electron enters the p-orbital of the outermost shell
P-block elements include groups 13 to 18 in the periodic table.
How many groups are in the p-block?
6 groups (13 to 18)
Each group corresponds to the number of electrons that can occupy the p-subshell.
What elements constitute Group 16?
- Oxygen (8O)
- Sulphur (16S)
- Selenium (34Se)
- Tellurium (52Te)
- Polonium (84Po)
Group 16 is also known as the oxygen family or chalcogens.
What is the significance of the term ‘chalcogens’?
It means ‘ore forming’
Many metal ores are oxides or sulphides.
What percentage of air volume is composed of oxygen?
20.95%
Oxygen is the most abundant element on Earth.
What is the occurrence of sulphur in the Earth’s crust?
0.034% by mass
Mainly found in combined forms as sulphates and sulphides.
What elements constitute Group 17?
- Fluorine (9F)
- Chlorine (17Cl)
- Bromine (35Br)
- Iodine (53I)
- Astatine (85At)
Group 17 is known as halogens.
Why are halogens highly reactive?
Due to high electronegativities
They are not found in a free state.
What is the main source of chlorine in seawater?
Sodium chloride (NaCl)
Seawater contains chlorides, bromides, and iodides.
What are the main noble gases in Group 18?
- Helium (2He)
- Neon (10Ne)
- Argon (18Ar)
- Krypton (36Kr)
- Xenon (54Xe)
- Radon (86Rn)
All noble gases except radon occur in the atmosphere.
What is the general electronic configuration for Group 16 elements?
ns2np4
This configuration is crucial for understanding their chemistry.
What happens to atomic and ionic radii down the groups?
They increase due to an increase in the number of shells
Across periods, they decrease due to increased effective nuclear charge.
What is the trend of ionization enthalpy in groups 16, 17, and 18?
High ionization enthalpy that decreases down the group
Increases across periods with increasing atomic number.
What are the common oxidation states of Group 16 elements?
- -2
- +2
- +4
- +6
Oxygen typically shows -2, +2 in OF2, and -1 in peroxides.
What is the most electronegative element in the periodic table?
Fluorine
Halogens have very high electronegativity.
What is the anomalous behavior of oxygen attributed to?
- Small atomic size
- High electronegativity
- Absence of d-orbitals
These factors lead to unique properties compared to other group 16 elements.
What is the state of oxygen at room temperature?
Gas
Other group 16 elements are solids at room temperature.
What is the typical covalency of oxygen?
2
Other group 16 elements can exceed a covalency of four.
What defines the physical state of halogens at room temperature?
- Fluorine and chlorine are gases
- Bromine is a liquid
- Iodine is a solid
This reflects their molecular weights and interactions.
What is the bond dissociation enthalpy order for halogen molecules?
Cl—Cl > Br—Br > F—F > I—I
This indicates the strength of the bonds among halogens.
What is the electron gain enthalpy trend in groups 16 and 17?
Becomes less negative down the group
Smaller atomic size results in less negative values for oxygen and fluorine compared to their heavier counterparts.
What is the significance of the inert pair effect?
Stability of higher oxidation states decreases down the group
This effect explains the behavior of elements in groups 13 to 16.
What characterizes the chemical behavior of noble gases?
They are zero valent and exist as monoatomic
This is due to their stable electronic configuration and lack of tendency to gain or lose electrons.
What oxidation states occur in oxides and oxoacids of Cl and Br?
+4 and +6