pKa of functional groups Flashcards

1
Q

alkyl alcohol

A

polar, neutral

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2
Q

ether

A

polar, neutral

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3
Q

ester

A

polar, neutral

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4
Q

sulfonic acid ester

A

polar, neutral

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5
Q

amide

A

polar, neutral

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6
Q

nitrile or cyano

A

polar, neutral

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7
Q

amine oxide

A

polar neutral

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8
Q

quaternary ammonium salt

A

polar, neutral

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9
Q

aldehyde

A

polar, neutral

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10
Q

ketone

A

polar, neutral

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11
Q

thioether

A

polar, neutral

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12
Q

sulfoxide

A

polar, neutral

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13
Q

sulfone

A

polar, neutral

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14
Q

phenol

A

acidic,
9-11

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15
Q

sulfonamide

A

acidic,
9-10

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16
Q

imide

A

acidic,
9-10

17
Q

N-aryl-sulfonamide

A

acidic
6-7

18
Q

sulfonimide

A

acidic
5-6

19
Q

alkylcarboxylic acid

A

acidic
5-6

20
Q

Arylcarboxylic Acid

A

acidic,
4-5

21
Q

sulfonic acid

A

0-1 pka
acidic

22
Q

imine

A

basic
pka: 3-4

23
Q

arylamine

A

basic,
4-5

24
Q

aromatic amine

A

basic
5-6

25
Q

alkylamine (primary to tertiary)

A

primary 9-10
secondary 10-11
tertiary not given
basic

26
Q

amidine

A

10-11
basic

27
Q

guanidine

A

12-14
basic