Polymers Flashcards

1
Q

Describe what is meant by an addition polymer

A

In addition polymers, the monomers are alkenes.

In addition polymerisation reactions, many small molecules
(monomers) join together to form very large molecules (polymers)

A large molecule made from alkene monomers which bond together by opening up their double bonds and forming long chains

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2
Q

what is an addition reaction

A

reactions where the double bond in an alkene opens up to leave a single bond and a new atom is added to each carbon

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3
Q

What type of molecules are used to make polymers by addition polymerisation

A

Alkenes can be used to make polymers such as poly(ethene) and poly(propene) by addition polymerisation.

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4
Q

difference between alkenes and addition polymers in terms of structure

A

The monomer has a double carbon to carbon bond but the polymer has single carbon to carbon bonds

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5
Q

what is a polymer

A

A polymer is made by joining together thousands of small identical molecules

A long chain molecule that is formed by joining lots of smaller molecules (monomers) together

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6
Q

What is a monomer

A

a small molecule that can be joined together with other small molecules to form a polymer

these identical molecules are called monomers

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7
Q

The _______ molecules have joined together to form the _________

A

The monomer molecules have joined together to form the polymer

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8
Q

What is a repeating unit

A

the shortest repeating section of a polymer

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9
Q

Draw diagrams to represent the formation of an addition polymer

ethene

A

see cgp book

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10
Q

Two different types of polymers

A

Addition polymers
Condensation polymers

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11
Q

poly meaning

A

poly means many

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12
Q

draw the polymer poly(ethene)

A

https://images.ukessays.com/180520/2/0636388.007.jpg

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13
Q

draw the repeating unit of poly(ethene)

A

https://www.tutormyself.com/wp-content/uploads/polyethene-repeat-unit-233x300.png

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14
Q

draw the structure of the monomer ethene

A

https://bam.files.bbci.co.uk/bam/live/content/z8vmv9q/medium

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15
Q

formula of poly(ethene) draw the structure

A

https://bam.files.bbci.co.uk/bam/live/content/zqrhrwx/medium

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16
Q

https://bam.files.bbci.co.uk/bam/live/content/zqrhrwx/medium

what does the n represent

A

The n represents a large number
This tells us that the polymer consists of a large number of repeating units

17
Q

Features of addition polymers

A

In addition polymers, the repeating unit has the same atoms as the monomer.
This is because, no other molecule is formed in the reaction
when we make an addition polymer All of the atoms in the monomer end up in the polymer

The repeating unit does not contain a double bond

The monomers that make up addition polymers have a double covalent bond

18
Q

reaction of conversion of ethene to poly(ethene)

show an equation for the polymerisation of poly(ethene).

A

https://bam.files.bbci.co.uk/bam/live/content/zqrhrwx/medium

19
Q

In addition polymers explain why the repeating unit has the same atoms as the monomer.

A

In addition polymers, the repeating unit has the same atoms as the monomer.
This is because, no other molecule is formed in the reaction

20
Q

draw poly(propene)

A

https://bam.files.bbci.co.uk/bam/live/content/z9vmv9q/small

https://bam.files.bbci.co.uk/bam/live/content/ztjbjty/small

21
Q

The diagram shows the structure of propene. Deduce the structure of poly(propene), and use this to show an equation for the polymerisation of propene.

A

https://bam.files.bbci.co.uk/bam/live/content/ztjbjty/small

22
Q

describe what happens during an addition reaction

A

during an addition reaction, lots of unsaturated monomer molecules (alkenes) open up their double bons and join together to form polymer chains
This is called addition polymerisation

23
Q

Describe what is meant by a condensation polymer

A

a large molecule made from monomers with at least two different functional groups that react together to form chains
A small molecule is lost for each bond formed

24
Q

Draw the repeating unit for a condensation polymer

25
Describe what happens during condensation polymerisation
In condensation polymers, the monomers are not alkenes When these monomers react, we lose small molecules such as water
26
how condensation polymers are formed
With condensation polymers, we start with two different monomers Each monomer has two of the same functional groups reacting a carboxylic acid with an alcohol produces an ester + water To form the condensation polymer, we react our two monomers together These react to form an ester and water We can continue to add monomers to either end and this allows us to produce a long polymer
27
ethane diol HO - CH2 - CH2 - OH hexanedioic acid HOOC - CH2 - CH2 - CH2 - CH2 - COOH what do these monomers have in common
Each monomer has two of the same functional groups Ethane diol has two alcohol groups hexanedioic acid has two carboxylic acid groups HO - BOX - OH HOOC - BOX - COOH
28
condensation polymerisation of HO-BOX-OH and HOOC - BOX - COOH DRAW STRUCTURAL AND DISPLAYED FORMULA LABEL ESTER LINK
First react them together alcohol loses H carboxylic acid looses OH HO - BOX - OOC - BOX - COO - BOX - OOC- BOX - OH H2O IS PRODUCED https://cdn.savemyexams.com/cdn-cgi/image/w=1280,f=auto/uploads/2020/01/Forming-Terylene.png ESTER LINK
29
HO - BOX - OOC - BOX - COO - BOX - OOC- BOX - OH what is this type of polymer called
This type of polymer is called a polyester
30
draw repeating unit HO - BOX - OOC - BOX - COO - BOX - OOC- BOX - OH
- BOX - OOC - BOX - COO -
31
draw formula for polyester HO - BOX - OOC - BOX - COO - BOX - OOC- BOX - OH
-(- BOX - OOC - BOX - COO -)-n
32
draw the structure of this following polymerisation 1000 HO-BOX-OH + 1000HOOC-BOX-COOH
-(-BOX - OOC - BOX - COO -)100