Polymers Flashcards

(49 cards)

0
Q

Give an example of semi synthetic polymer

A

Cellulose acetate(RAYON)

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1
Q

How are monomers linked to each other?

A

By covalent bonds

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2
Q

What is the structure of high density polythene?

A

Linear

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3
Q

Low density polythene is classified as

A

Branched chain polymer

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4
Q

How are network polymers formed?

A

Formation of strong covalent bonds between linear polymers

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5
Q

Dacron is a condensation polymer which is also known as

A

Terylene

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6
Q

How are polymers classified on the basis of molecular forces

A
  1. Elastomers
  2. Fibres
  3. Thermosetting polymers
  4. Thermoplastic polymers
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7
Q

Elastomers are held together by…..

Example: neoprene ,Buna S ,Buna N

A

Weak Vanderwaal forces

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8
Q

Vulcanised rubber with 25% S is c’d

A

Ebonite

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9
Q

Fibres r held together by…..

Eg:- polyamides and polyesters

A

H-bonding

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10
Q

Thermoplastics are..?

A

Polythene, PVC, polystyrene

Become soft on heating and hard on cooling.

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11
Q

Formaldehyde resins and Bakelite are examples of…

A

Thermosetting polymers

On heating form cross link and become infusible on cooling

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12
Q

Addition polymerisation is also c’d

A

Chain growth polymerisation

Condensation= step growth polymerisation

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13
Q

What is the most common mode of addition polymerisation?

A

Free radical mechanism

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14
Q

Initiator used in prep of polythene is

A

Benzoyl peroxide

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15
Q

Conditions for manufacture of low density polythene

A

P= 1000-2000atm
T=350-570K

Peroxide catalyst

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16
Q

Conditions for high density polythene

A

Hydrocarbon solvent
T=333-343K
P=6-7 atm

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17
Q

Catalyst used in manufacturing of HDP

A

Ziegler natta catalyst (TiCl4)

Triethylaluminium

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18
Q

Monomer of Teflon is-

A

Tetrafluoroethene

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19
Q

Catalyst used in manufacturing of Teflon is

A

Persulphate catalyst

(NH4)2S2O8

20
Q

Wool is substituted by

A

Acrilan or orlan made of PAN

21
Q

What r the monomers of Dacron?

A

Ethylene glycol & terephthallic acid

22
Q

Monomer of Nylon6 is

23
Q

Polyesters are polycondensation products of..

A

Dicarboxylic acids and diols

24
Catalyst used in manufacturing Dacron
Zinc acetate-antimony
25
Oldest synthetic polymers are
Phenol formaldehyde polymers
26
What is the initial product of condensation reaction of phenol & formaldehyde
Novolac
27
The infusible solid mass formed after heating Novolac with formaldehyde is called..
Bakelite
28
Unbreakable crockery is made of
Melamine
29
Buna S is a substitute for
Natural rubber
30
What is rubber latex?
Colloidal dispersion of rubber in water
31
Natural rubber is the polymer of
Isoprene (2-methyl1,3-butadiene) Also called cis-1,4-poly isoprene
32
Monomer of PHBV
3-hydroxybutanoic acid | 3-hydroxypentanoic acid
33
Nylon2,6 is polymer of
Glycine & amino caproic acid
34
Glyptal is polymer of?
Ethylene glycol & phthallic acid
35
Monomers of nylon 6,10
Hexamethylene diamine & sebasic acid
36
Monomer of polyurethane
Ethylene glycol & toluene-m-cyanate
37
Monomer of starch ?
a-D-glucose It is also the monomer of glycogen
38
Monomer of cellulose
B-D-glucose
39
Neoprene is polymer of
Chloroprene (2-chloro-1,3-butadiene)
40
Acrilan is
PAN
41
During polymerisation nylon 66 is obtained in which form
Liquid state
42
Vulcanised rubber is
Low water absorbing Resistant to oxidation Good elasticity
43
Plexiglass is commercial name for
Poly methyl methacrylate(PMMA)
44
Polymer used in making bulletproof glass is
Lexan
45
Rubber used for manufacturing tyres is vulcanised with
3-10% S | (5%) ncert
46
Petrol hoses are made of
Buna N
47
Monomer of polyvinyl polythene is
1,3-butadiene
48
Polymer used in orthopaedic devices and sustained drug release is
PHBV