Polymers ORGANIC Flashcards
(34 cards)
What is condensation polymerisation?
Reaction in which a polymer is produced by repeated condensation reactions between monomers
How are natural condensation polymers formed?
By elimination of water
How can polymers be identified?
By ester or amide bonds linking monomers
What can form condensation polymers?
Dicarboxylic acids and diols
Dicarboxylic acids and diamines
Amino acids
How are polyesters formed?
Reaction linking dicarboxylic acid monomers and diol monomers by ester bonds
What is produced in formation of polyesters? How?
Water molecule
Formed from OH group from COOH on acid and H from alcohol
How are hydroxycarboxylic acids used as monomers?
Single monomer containing both key functional groups
What are polyamides?
Polymers where repeating units are bonded by amide links
What forms a polyamide?
Diamide and dicarboxylic acid
What can be used in place of a dicarboxylic acid to form a polyamide?
Diacyl
Dioyl dichlorides
What is produced in formation of polyamides? How?
Water molecule
Formed from OH group from COOH on acid and H from diamine
What are amino acids?
Polymers made of amino acid monomers
What structure do amino acids have?
Aminocarboxylic acid structure
What determines the properties of an amino acid?
R group side chain
How can different amino acids be identified?
By unique R group
What are dipeptides?
2 amino acids polymerised together
What are polypeptides?
2 or more amino acids polymerised together
What is polyethylene terephthalate (PET)?
A thermoplastic which can be repeatedly heated to soften and melt and cooled to solidify
What is a common artificial polyamide?
Nylon
What is nylon made from?
Diamine and dicarboxylic acid, each containing 6 carbon atoms
What can be used to break down polyesters and polyamides?
Hydrolysis reactions
What happens to polyesters and polyamides at landfill?
Broken down easily and products used for other applications
How can simple esters and amides be hydrolysed?
By reaction with aqueous acids or bases into carboxylic acids and alcohols or amines
What are esters hydrolysed into?
Carboxylic acids and alcohols