Polymers ORGANIC Flashcards

(34 cards)

1
Q

What is condensation polymerisation?

A

Reaction in which a polymer is produced by repeated condensation reactions between monomers

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2
Q

How are natural condensation polymers formed?

A

By elimination of water

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3
Q

How can polymers be identified?

A

By ester or amide bonds linking monomers

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4
Q

What can form condensation polymers?

A

Dicarboxylic acids and diols
Dicarboxylic acids and diamines
Amino acids

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5
Q

How are polyesters formed?

A

Reaction linking dicarboxylic acid monomers and diol monomers by ester bonds

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6
Q

What is produced in formation of polyesters? How?

A

Water molecule
Formed from OH group from COOH on acid and H from alcohol

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7
Q

How are hydroxycarboxylic acids used as monomers?

A

Single monomer containing both key functional groups

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8
Q

What are polyamides?

A

Polymers where repeating units are bonded by amide links

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9
Q

What forms a polyamide?

A

Diamide and dicarboxylic acid

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10
Q

What can be used in place of a dicarboxylic acid to form a polyamide?

A

Diacyl
Dioyl dichlorides

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11
Q

What is produced in formation of polyamides? How?

A

Water molecule
Formed from OH group from COOH on acid and H from diamine

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12
Q

What are amino acids?

A

Polymers made of amino acid monomers

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13
Q

What structure do amino acids have?

A

Aminocarboxylic acid structure

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14
Q

What determines the properties of an amino acid?

A

R group side chain

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15
Q

How can different amino acids be identified?

A

By unique R group

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16
Q

What are dipeptides?

A

2 amino acids polymerised together

17
Q

What are polypeptides?

A

2 or more amino acids polymerised together

18
Q

What is polyethylene terephthalate (PET)?

A

A thermoplastic which can be repeatedly heated to soften and melt and cooled to solidify

19
Q

What is a common artificial polyamide?

20
Q

What is nylon made from?

A

Diamine and dicarboxylic acid, each containing 6 carbon atoms

21
Q

What can be used to break down polyesters and polyamides?

A

Hydrolysis reactions

22
Q

What happens to polyesters and polyamides at landfill?

A

Broken down easily and products used for other applications

23
Q

How can simple esters and amides be hydrolysed?

A

By reaction with aqueous acids or bases into carboxylic acids and alcohols or amines

24
Q

What are esters hydrolysed into?

A

Carboxylic acids and alcohols

25
What are amides hydrolysed into?
Amines
26
What three ways are there of disposing of polymers?
Landfill Incineration Recycling
27
What are the advantages of landfill disposal of polymers?
Buried at specific contained site Biodegradable polymers degrade slowly
28
Which polymers are biodegradable?
Polyesters and polyamides
29
Which polymers are not biodegradable?
Polyalkenes
30
What are the disadvantages of landfill disposal of polymers?
Limited land available Slow degradation of plastics Leaching of toxic compounds Gas emissions
31
What are the advantages of incineration disposal of polymers?
Less space than landfill Energy released can generate electricity Prevents build up of polymers in environment
32
What are the disadvantages of incineration disposal of polymers?
Increase in CO₂ Toxic gas emissions and particulates
33
What are the advantages of recycling of polymers?
Reuse and conservation of finite hydrocarbon resources Reduction of waste in landfill
34
What are the disadvantages of recycling of polymers?
Collection, sorting, separating, remoulding all require energy Time consuming Expensive