qualitive analysis Flashcards
(6 cards)
test for carbonate
negative anion
-bubble gas through limewater to test for CO2
- if CO2 is detected it will turn cloudy
testing for a sulphate
testing for negative anions
acidified BaCl2 is used to test for sulphate ions , if the solution contains sulphate ions a white precipice will form
-sulphuric acid cannot be used to test for sulphate ions because it already contains sulphate ions
testing for halide ions
use nitric acid then silver nitrate solution
fluorine-no precipitate
chlorine-white precipitate
bromine- cream precipitate
iodine- pale yellow precipitate
the role of nitric acid is to react any carbonates to prevent formation of the precipitate Ag2CO3
ammonia solution
you can use ammonia solution to differentiate if the colours look similar
silver chlorine - dilute ammonia
silver bromide - concentrated ammonia
silver iodide - does not react with ammonia , its too insoluble
sequence of tests
carbonate
sulphate
halide
testing for positive ions ( cations )
test for ammonium NH4+
warm NaOH(aq) forming NH3 gas
ammonia gas can be identified by its smell or by turning red litmus paper blue