quiz 5 Flashcards

(48 cards)

1
Q

law of conservation of energy formula

A

(KE + PE)initial = (KE + PE)final

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2
Q

how many calories is in 1 kcal?

A

1000 cal per 1 kcal

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3
Q

how many J in 1 Kilowatt-hour

A

3.60 x 10^6 J per Kilowatt-hour

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4
Q

What is a system?

A

system consists of those molecules which are reacting

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5
Q

What is the surroundings in an experiment?

A

everything else that is not the system?

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6
Q

what are the three types of systems?

A

open, closed, and isolated

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7
Q

what is an open system?

A

energy can flow in and out

matter can flow in and out

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8
Q

what is a closed system?

A

if closed beaker, matter can not flow in or out

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9
Q

what is a closed system?

A

if closed beaker, matter can not flow in or out

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10
Q

what is an isolated system?

A

insulated, energy cant flow in or out

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11
Q

what are the 2 types of energy transfer?

A

exothermic and endothermic

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12
Q

what is exothermic?

A

heart flows out from the system to the surrondings

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13
Q

what is endothermic?

A

heat flows in from the surrounding to the system

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14
Q

endo or exothermic: propane burning?

A

exothermic

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15
Q

endo or exothermic: food cooking?

A

endothermic

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16
Q

endo or exothermic: dry ice subliming?

A

endothermic

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17
Q

endo or exothermic: metal reacting with acid?

A

exothermic

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18
Q

what is internal energy (U)?

A

sum of PE and KE of a system

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19
Q

what are the properties of a state function?

A

the value does not depend on how it got there, change only asks for start and end points, state functions deal with change

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20
Q

what is the opposite of a state function

A

a path function

21
Q

what is the formula for deltaUniverse

A

deltaSystem + deltaSurrounding=0

22
Q

why is deltaSurroundings + deltaSystem =0?

A

because energy is conserved, theres no change

23
Q

Why is deltaSystem + deltaSurrounding=0?

A

because energy is conserved; no change

24
Q

what is the equation of deltaU

25
what does q stand for
heat
26
what does w stand for
work
27
what is there no delta in front of q and w
because you can not keep heat or work; also it is a transfer of work
28
work formula
w= -P(deltaV)
29
What happens if the gas in a system expands?
deltaV > 0 | w<0
30
What happens if the gas in a system compresses?
deltaV<0 | w>0
31
What happens if the gas in a system does not change in volume?
deltaV=0 | w=0
32
what happens (in terms of heat and work) in a combustion reaction?
heat is transferred out of the fuel | work is being done by the fuel
33
if the fuel is the system in a combustion reaction, what are the signs of q and w and deltaU?
q<0 w<0 deltaU<0
34
What are the two heat equations?
q=C (deltaT) | q=m(Cs)deltaT
35
what is the different between the two heat equations?
the one with mass and specific heat (Cs) is used if dealing with a pure substance
36
what is the sign of heat if it is cooling down?
negative
37
is cooling down endo or exothermic reactions?
exothermic
38
what kind of sign will heat have if it is an exothermic reaction?
negative
39
what is constant in a bomb calorimetry
volume
40
since volume is constant in a bomb calorimetry what is the equation for work
work = 0 so: -PdeltaV=0
41
what kind of system is a bomb calorimetry?
isolated
42
since the bomb calorimetry is an isolated system what happens to q?
The sum is =0
43
how do you tell if volume will increase
look at balanced equation and moles
44
in an isolated system what happens to deltaU
it would always be the same because it is a state function
45
what is the formula used when working with a bomb calorimetery
qrxn + qcal = 0 | qrxn + C(deltaT) = 0
46
what happens to the pressure in a coffee cup calorimetry?
pressure stays constant
47
what happens to deltaUuniverse in a coffee cup calorimetry?
delaUuniverse=0
48
what is the equation for an aqueous reaction?
0= qrxn + qwater + qcal