Random Flashcards

(10 cards)

1
Q
What is 
   Acetylsalicylic acid 
   HNO3-
   Benzene with an acyl group 
   Sodium sterate
   Mixture of esters
   Glycerol
   Esters 
   Quaternary ammonium salt 
   Optical isomers 
   Aromatic nitro compounds
A
Aspirin 
Intermediate 
Intermediates 
Soap
Biodiesel 
Food and glue 
Perfume 
Surfactant 
Drugs 

Explosives
Decompose with explosive violence due to energetically unstable
Aromatic amine manufacture

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2
Q

Nucleophillic addition
What’s the reagent with
Hydride
Cyanide

A

NaBH4 in aqueous ethanol

Dilute H2SO4 with KCN

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3
Q
How many lone pairs does 
   O have in H2O
   N have in NH3 
   N have in RNH2 
   O have in ROH
A

2
1
1
2

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4
Q

Electrophillic Addition
Where does the first arrow come from?
What are the reagents and conditions for it with NO2?
What are acyl benzene a good for use in?

A

The delocalised ring
Conc HNO3 and H2SO4 warmed at 50c
Manufacture of subtituted aromatic compounds

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5
Q

Why are acyls good for addition elimination?

A

Possess good leaving groups
Cause electron withdrawal of adjacent carbon
Leads to attack from nucleophile

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6
Q

What is
Oleic acid
Steric acid
Unoleic acid

A

Olive oil and animal fat
Animal fats
Corn oil

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7
Q

What are the catalysts for esterification?

What do you do?

A

HCl H2SO4 H3PO4

Reflux with the acid

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8
Q

Optical isomers
Chemical properties are? Except with?
Why will one isomer work as a drug and one not?
What are some sold as?

A

Identical except with other optically active molecule of active ingredient fits receptor so shape important
Racemate

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9
Q

Preparing primary aliphatic amines

A

Heat haloalkane with xs ammonia dissolved in ethanol

Heat haloalkane with KCN dissolved in ethanol and reduce resulting nitrile

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10
Q

How does an electron withdrawing molecule increase ability to act like an acid?

A

Weakens OH bond

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