Rates of Reaction / Reversible Reactions Flashcards
(33 cards)
What is the rate of a reaction? - Rates of Reaction
A measure of how quickly a reactant is used up or how quickly a product is formed
What is collision theory? - Rates of Reaction
The theory that for a chemical reaction to happen reactant particles must collide with each other and the particles must have enough energy to react
What is a successful collision? - Rates of Reaction
A collision between reactant particles that has enough energy to create a reaction
What importance is activation energy for successful reactions? - Rates of Reaction
If particles do not have sufficient activation energy (the minimum amount of energy that colliding particles must have in order to react) a reaction won’t take place
What 2 ways can be used to calculate the mean rate of a reaction? What unit is used - Rates of Reaction
Rate of reaction = quantity of reactant used / time taken
OR quantity of product formed / time taken
Units in g/s or g/minute
How can the volume of gas produced in a reaction be measured? - Rates of Reaction
A gas syringe can be placed in a bung on a conical flask and it will measure the volume of gas produced
How can the gradient of a rate of reaction graph be useful to us? - Rates of Reaction
The gradient of the line shows the rate of reaction (steep gradient = quick reaction)
How does the concentration of reactants affect the rate of reaction? - Rates of Reaction
The reactant particles become more crowded as there are more of them, which increases the frequency of successful collisions and increases the rate of a reaction
How does the pressure of reactants (gas) affect the rate of reaction? - Rates of Reaction
By increasing the pressure, reactant particles become more crowded, increasing the frequency of successful collisions, and increasing the rate of reaction
How can you calculate the rate of a reaction at a given stage of the reaction? - Rates of Reaction
By drawing a tangent to the curve on the graph, calculate the gradient of this tangent to find the rate of the reaction
How does surface area : volume ratio affect the rate of a reaction? - Rates of Reaction
The higher the surface area to volume ratio, more reactant particles are exposed at the surface. This means that the frequency of successful collisions between reactants increases, increasing the rate of reaction
How does temperature affect the rate of a reaction? - Rates of Reaction
It increases the internal (kinetic) energy of the particles, meaning more particles have activation energy, meaning the number of successful collisions increases. Rate increases.
What is a catalyst? - Rates of Reaction
A substance that increases the rate of a chemical reaction without being used up
How do catalysts work? - Rates of Reaction
Provides an alternative reaction pathway with a lower activation energy. Increases the frequency of successful collisions
How do a catalysts effects appear on a reaction profile? - Rates of Reaction
The activation energy is lower than previously, therefore the gradient of the loop on the graph is smaller
What is a reversible reaction? - Reversible Reactions
A reaction where the reactants can be converted into products and products back into reactants
What rule is there for reversible reactions regarding endothermic and exothermic reactions? - Reversible Reactions
If a reaction is endothermic one direction, then it is exothermic in the other
Which direction is the equilibrium of a forward and backward reaction? - Reversible Reactions
The forward reaction goes to the right
The backward reaction goes to the left
How does a reversible reaction work in terms of hydrated copper sulfate? - Reversible Reactions
As the hydrated copper sulfate is heated, the water molecules are driven off, leaving ANHYDROUS copper sulfate. By adding water, the copper sulfate becomes hydrated again
What is an equilibrium? - Reversible Reactions
A state where the forward and backward reactions are happening at the same rate, with the concentrations of all reactants being constant
What is dynamic equilibrium? - Reversible Reactions
A state of balance between continuing processes
Describe the Haber process - Reversible Reactions
Nitrogen gas is reacted with hydrogen gas to make ammonia gas. The forward reaction is exothermic
What is Le Chatelier’s principle? - Reversible Reactions
The idea that if the conditions of a reversible reaction are altered, the equilibrium will shift to oppose the change
How can the reaction conditions be changed in a reversible reaction? - Reversible Reactions
Changing the PRESSURE
Changing the CONCENTRATION
Changing the TEMPERATURE