Reaction Intermediate Flashcards

(20 cards)

1
Q

hybridisation of carbocation

A

sp2

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2
Q

hybridisation of carbanion

A

sp3

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3
Q

hybridisation of free radical

A

sp2

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4
Q

magnetic behavior of free radical

A

paramagnetic

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5
Q

magnetic behavior of carbanion

A

diamagnetic

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6
Q

carbene is a

A

neutral specie

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7
Q

hybridisation of singlet carbene

A

sp2

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8
Q

hybridisation of triplet carbene

A

sp

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9
Q

magnetic behavior of singlet carbene

A

diamagnetic

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10
Q

magnetic behavior of triplet carbene

A

paramagnetic

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11
Q

shape of singlet carbene

A

bent/ v-shape

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12
Q

shape of triplet carbene

A

linear

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13
Q

carbene has ………… electrons

A

6 electrons ( 2bp and 2 non-bonding electrons)

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14
Q

singlet carbene ………… hund’s rule

A

violates

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15
Q

triplet carbene………….. hund’s rule

A

follows

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16
Q

stability of carbene in :ch2

17
Q

spin state

18
Q

stability of singlet>triplet

A

:CBr2 / :CCl2 ( due to backbonding)

19
Q

carbene is

A

an intermediate and NOT A PRODUCT

20
Q

formation of carbene

A
1. CHCl3/CHF2Cl....etc with BASE like 
   KOH/NaOH/C2H5O-/C6H5O-.....etc
2. Pyrolysis/Photolysis of DIAZOMETHANE (CH2N2)
     CH2=N=N   -------->  N2^ + :CH2
3. KETENES
      CH2=C=O   -------->  CO2^ + :CH2