Reaction Intermediate Flashcards
(20 cards)
hybridisation of carbocation
sp2
hybridisation of carbanion
sp3
hybridisation of free radical
sp2
magnetic behavior of free radical
paramagnetic
magnetic behavior of carbanion
diamagnetic
carbene is a
neutral specie
hybridisation of singlet carbene
sp2
hybridisation of triplet carbene
sp
magnetic behavior of singlet carbene
diamagnetic
magnetic behavior of triplet carbene
paramagnetic
shape of singlet carbene
bent/ v-shape
shape of triplet carbene
linear
carbene has ………… electrons
6 electrons ( 2bp and 2 non-bonding electrons)
singlet carbene ………… hund’s rule
violates
triplet carbene………….. hund’s rule
follows
stability of carbene in :ch2
singlet
spin state
l2sl+1
stability of singlet>triplet
:CBr2 / :CCl2 ( due to backbonding)
carbene is
an intermediate and NOT A PRODUCT
formation of carbene
1. CHCl3/CHF2Cl....etc with BASE like KOH/NaOH/C2H5O-/C6H5O-.....etc 2. Pyrolysis/Photolysis of DIAZOMETHANE (CH2N2) CH2=N=N --------> N2^ + :CH2 3. KETENES CH2=C=O --------> CO2^ + :CH2