reactions of the main functional groups - flow chart Flashcards
ch28.3
alkene –> haloalkane
hydrogen halide
alkene –> primary alcohol
HYDRATION: H3PO4/H20
primary alcohol –> alkene
H2SO4
primary alcohol –> haloalkane
Sodium halide/ H2SO4
haloalkane –> primary alcohol
NaOH(aq)
haloalkane –> amine
NH3/ethanol
haloalkene –> nitrile
NaCN
nitrile –> amine
REDUCTION: H2/Ni
nitrile –> carboxylic acid
HYDROLYSIS: H20/HCl
primary alcohol –> aldehyde
OXIDATION:K2Cr2O7/H2SO4
aldehyde –> primary alcohol
REDUCTION: NaBH4/H2O
primary alcohol –> ester
ESTERIFICATION: carboxylic acid/ H2SO4
aldehyde –> hydroyxlnirtile
NUCLEOPHILLIC ADDITION: NaCN/H+
aldehyde –> carboxylic acid
OXIDATION: K2CR2O7/H+
carboxylic acid –> acyl chloride
SOCl2
acyl chloride –> carboxylic acid
H2O
carboxylic acid –> ester
ESTERIFICATION: alcohol/H2SO4
ester –> carboxylic acid
HYDROLYSIS: dilute acid
acyl chloride –> primary amide
NH3
acyl chloride –> secondary amide
primary amine
acyl chloride –> ester
alcohol
ester –> sodium salt of carboxylic acid and alcohol
ALKALINE HYDROLYSIS: NaOH