Reactivity 1 Flashcards

(44 cards)

1
Q

What happens to the energy in an exothermic reaction?

A

Excess energy is given out to the surroundings as heat

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2
Q

What happens to the energy in an endothermic reaction?

A

Excess energy required is taken in from the surroundings

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3
Q

Do exothermic reactions have a positive or negative ∆H value?

A

Negative

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4
Q

Do endothermic reactions have a positive or negative ∆H value?

A

Positive

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5
Q

What is ΔH⦵ measured in?

A

kJ mol^-1

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6
Q

What is ΔH⦵?

A

Standard enthalpy change

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7
Q

Is energy required to form a chemical bond?

A

No

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8
Q

Is energy required to break a chemical bond?

A

Yes

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9
Q

What is the formula to calculate enthalpy changes?

A

ΔH⦵ = ΔH⦵(bonds broken) - ΔH⦵(bonds formed)

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10
Q

If you are doing a simultaneous equation and you rearrange the formula, what happens to ΔH?

A

Reverse the sign

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11
Q

Arrange from strongest to weakest: single covalent bond, double covalent bond, triple covalent bond

A

Triple covalent, double covalent, single covalent

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12
Q

What is the idea with the Hess’ Law problems for the indirect determination of an enthalpy change? (triangles)

A

A going directly to C or through B

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13
Q

How do you find the bond enthalpy in the indirect determination of an enthalpy change?

A

Figure out the number of bonds broken, and divide previous answer by said number

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14
Q

Specific energy of a fuel formula

A

energy released from the fuel/mass of fuel consumed

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15
Q

Units for specific energy of a fuel

A

kJ kg^-1

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16
Q

If you know the enthalpy of combustion, how do you find the specific energy?

A

Dividing by the molar mass

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17
Q

Three main fossil fuels

A

Coal, crude oil, natural gas

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18
Q

How is oil and natural gas produced?

A

Anaerobic decomposition of marine organisms

19
Q

How is coal produced?

A

Terrestrial vegetation

20
Q

Advantages of natural gas

A

Clean, easily transported, higher specific energy than coal or oil

21
Q

Disadvantages of natural gas

A

Contributes to global warming, limited lifespan, uneven distribution

22
Q

Advantages of oil

A

Easily transported, feedstock for organic chemicals, convenient fuel for vehicles

23
Q

Disadvantages of oil

A

Contributes to global warming, limited lifespan, risk of marine pollution (oil spills)

24
Q

Advantages of coal

A

Present in large quantities, feedstock for organic chemicals, releases more energy than renewable sources, longer lifespan

25
Disadvantages of coal
Contributes to global warming, not as easily transported, mining coal is dangerous, dirty
26
What is the greenhouse effect?
Greenhouse gases absorbing some of the infrared heat from the earth and re-radiating it back into the earth.
27
What is a carbon footprint?
Total amount of greenhouse gases produced during human activities
28
What energy is converted in photosynthesis?
Light energy to chemical energy
29
What is the photosynthesis equation?
6CO2 + 6H20 → C6H12O6
30
What is biomass?
Organic material that can be used as an energy source
31
How is liquid fuel obtained from biomass?
Fermentation
32
What is the equation for obtaining liquid fuel from biomass?
C6H12O6 → 2C2H5OH + 2CO2
33
What is gasohol composed of?
10% ethanol and 90% gasoline
34
What is a common use for gasohol?
Used in unmodified cars, making them less reliant on crude oil.
35
Advantages of biomass
Renewable and always available, doesn’t significantly contribute to the greenhouse effect, safer to produce, reduces landfill amount
36
Disadvantages of biomass
Uses up land that could be used for animals, increases the use of fertilisers which could pollute water, removes nutrients from the soil, methods of conversion are small scale.
37
In what form is the energy given out during the combustion of hydrogen in oxygen to form water?
Electricity (not heat)
38
Do hydrogen fuel cells need an external source of electricity?
No
39
What is the product of hydrogen fuel cells?
Water
40
What are the electrolytes used in alkaline fuel cells?
NaOH or KOH
41
What is used as the electrolyte in an acidic fuel cell?
An acid
42
What is the overall reaction equation in alkaline and acidic fuel cells?
2H2 + O2 → 2H2O
43
What are the products of a methanol fuel cell?
Carbon dioxide and water
44
If a reaction is reversed, what happens to the ΔH value?
It switches (positive/negative, negative/positive)/changes the sign