Reactivity 2.1 Flashcards

(47 cards)

1
Q

What do chemical reactions show about products and reactants in a reaction?

A

The ratio

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2
Q

How does the balancing of a chemical equation relate to the Law of Conservation of Mass?

A

No matter can be created or destroyed, so the chemical equations must be balanced i.e. atoms in reactants = atoms in products

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3
Q

Reactants

A

Elements/compounds consumed in a chemical reaction

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4
Q

Products

A

Elements/compounds produced by a chemical equation

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5
Q

When is a chemical equation balanced?

A

When atoms in reactants = atoms in products

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6
Q

Steps for balancing a chemical reaction

A

Word equation, unbalanced chemical equation, balancing, symbols of state

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7
Q

What is a precipitate?

A

An insoluble ionic compound

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8
Q

Ionic compounds consisting of these ions are generally soluble (no exceptions)

A

Na+
K+
NH4+
NO3-
CH3COO-

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9
Q

Exceptions to ionic compounds containing ions of Cl-, Br-, I- being generally soluble

A

Ag+
Pb2+

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10
Q

Exceptions to ionic compounds consisting of ions of SO42-, Cr2O72- being generally soluble

A

Pb2+
Ba2+
Ag+
Ca2+

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11
Q

Exceptions to ionic compounds containing CO32-, PO43- and S2- being generally insoluble

A

Na+
K+
NH4+

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12
Q

Exceptions to ionic compounds containing OH- being generally insoluble

A

Na+
K+
NH4+
Ba2+
Ca2+

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13
Q

Ionic equation

A

Balanced equation which only contains species that underwent change during the chemical reactions i.e. only includes species that underwent bond breaking and/or bond making

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14
Q

Spectator ions

A

Ions (liquid or aqueous) that remain unchanged during the reaction

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15
Q

What happens to spectator ions in an ionic equation?

A

Omitted

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16
Q

In a precipitation reaction, which ions are included in the ionic equation?

A

Ions that eventually end up in precipitate

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17
Q

Steps for writing ionic equations

A

Write a full chemical equation for the reaction

Show the individual ions for any species that will be present as separate ions (liquid/ aqueous ionic compounds and aqueous acids)

Eliminate any spectator ions

Write the ionic equation

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18
Q

Which ions are written as separate ions in an ionic equation?

A

Liquid and aqueous ionic compounds

Aqueous acids

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19
Q

Element + oxygen ->

A

Elemental oxide

20
Q

Hydrocarbon + oxygen ->

A

Carbon dioxide and water

21
Q

Complete combustion

A

Hydrocarbon + oxygen -> carbon dioxide + water

22
Q

Reactive metal + water ->

A

Metal hydroxide + hydrogen

23
Q

Acid + metal ->

A

Salt + hydrogen

24
Q

Acid + base ->

A

Salt and water

25
Neutralisation reaction
Acid + base -> salt + water
26
Acid + metal carbonate ->
Salt + carbon dioxide + water
27
Acid + metal hydrogen carbonate ->
Salt + carbon dioxide + water
28
Which non-metals come in pairs?
N O F Cl Be I
29
Precipitation reaction reactants
Two aqueous solutions (ions swap)
30
What can ionic equations be written for?
Ionisation of acids in aqueous solutions Precipitation reactions
31
For a substance to dissociate into ions, it must
Be ionic or dissociate in water
32
Mass-mass stoichiometry
Write a balanced chemical equation for the reaction Convert known mass to moles Write the required mole ratio Use the mole ratio to calculate the moles of the unknown reactant/product Convert back to mass of unknown
33
Mole ratio for mass-mass stoichiometry
n(unknown) / n(known) = coefficient (unknown) / coefficient (known)
34
35
What equations can be used for mole-mole stoichiometry?
n = m / M n = PV / RT n = c x V n = V / Vm (at STP)
36
Avogardo’s law
Equal volumes of all gases measured under the same conditions of temperature and pressure contain equal numbers of molecules
37
What does Avogardo’s law mean in relation to stoichiometry?
Volume-volume stoichiometry can occur, with a volume ratio found in the same way as the mole ratio
38
What are the assumptions when doing Volume-Volume stoichiometry?
Pressure and temperature are the same
39
What is the limiting reagent?
Reactant that it is totally consumed when the reaction is completed
40
What does the limiting reactant determine?
The theoretical amount of product produced
41
How to identify the limiting reactant
Balanced chemical equation for the reaction Identify what you know about each reactant Convert known quantities to moles Divide the moles of each reactant by the corresponding coefficient Smallest value is the limiting reactant. Largest value = in excess
41
How to predict quantity of product from limiting reactant
Use mole ratio of n(unknown)/n(known) = coefficient (unknown) / coefficient (known)
42
Theoretical yield
Amount of product theoretically produced
43
Predicting quantity of the reactant in excess that will remain unreacted
n(excess)react / n(limiting) = coefficient excess / coefficient minting Then, n(excess)unreacted = n(excess)initial - n(excess)react
44
Percentage yield
Experimental yield / theoretical yield. X 100%
45
Atom economy
Molar mass of desired product / molar mass of all reactants. X 100%
45
Green chemistry
An approach to chemical research and engineering that seeks to minimise the production and release into the environment of hazardous substances