redox Flashcards
(28 cards)
define redox
reduction, oxidation
reaction occur together
smth must oxidise, smth must reduce
oxidise: individual element’s O.S. increases LHS -> RHS
reduces: individual element O.S. decreases LHS -> RHS
oxidation state vs oxidation number in olvl
same thing
any element oxidation state
always 0
ELEMENT HAVE NO CHARGE.
any ion oxidation state
charge, ion
i.e. Iron (II) oxidation state: +2
i.e. X 3- oxidation state -3
1 unit oxygen oxidation state (bonded 2 compound)
O: -2
EXCEPT FOR
hydrogen peroxide’s oxygen (H2O2): -1
i.e. Na2 O
Na: +1
Na2: +2
O: -2
O.S.: +2-2 = 0
1 unit hydrogen oxidation state (bonded 2 nonmetal)
+1
1 unit hydrogen oxidation state (bonded 2 metal)
-1
total oxidation state of compound
add up to Zero
total oxidation state of: OH-
NO3 2-
SO4 2-
CO3 2-
NH4 +
total oxidation state = charge
i.e.
SO4 2- total oxidation state: -2
1 unit O oxidation state: -2
4 unit O oxidation state: -8
Therefore, sulfur oxidation state: +6
does molar number (big number) affect oxidation state?
no
to find oxidation/reduction of X3 + y2 = y2x3 , look for:
X3’s OS or X’s OS?
X’s OS
look for it individual to compare (standardized)
to find out which oxidate, reduce, what to find?
- find O.S., all other element beside oxygen
O.S. of X (LHS) in XY > +2
O.S. of X(RHS) in XY > +3
Did X oxidise, or reduce?
- X in XY oxidised
- Oxidation State of X increases from +2 to +3 in XY
XY individual O.S. of Y (LHS) > 2-
XY individual O.S. of Y (RHS) > 3-
is Y
- Y in XY reduced
- Oxidation State of Y decreases from 2- to 3- in XY
most of time how to tell if not redox?
GUIDE, DONT WRITE IN EXAM!!
no free element
what is a free element
i.e. 2Fe, Cl2, Cr2
what is not a free element
i.e. Co3 2-, HNO3 -, Co2
shoe
4 definition of oxidation
SHOE
State - o.s. increase
Hydrogen - lose hydrogen
Oxygen - gain oxygen
Electron - lose electron
effect of oxidising agent on X
X -> oxidised
oxidising agent -> reduced
test for reducing agent
R: acidified KMno4 purple -> colourless
example of Oxidising agent
acidified potassium maganate(VII) KMnO4
example of reducing agent
potassium iodide solution
KI
test for oxidizing agent
R: potassium iodide soln. colourless -> brown
bromine maganate (III)
Which part does “III” belong to?
(III) belongs to Maganate
is hydrogen peroxide oxidising or reducing agent?
can act as BOTH
other oxidising agent beside Kmno4
other reducing agent beside KI
oxidising agent: Acidified potassium dichromate (K2Cr2O7)
reducing agent: aq iron (II) ion