reversable reactions Flashcards
(15 cards)
first stage of the contact process symbol and word equation
sulfur + oxygen → sulfur dioxide
S + O2 → SO2
sulfur is burned in the air to make sulfur dioxide
Second stage of the concept process
sulfer dioxide is oxidised to make sulfur trioxide (reversible reaction )
sulfur dioxide + oxygen —> sulfur trioxide
SO2 + O2 —> SO3
third stage of the contact process
Oleum is then made by dissolving sulfur trioxide in concentrated sulfuric acid.
The oleum is then converted to sulfuric acid by adding water.
SO3 + H2SO4 —> H2S2O7
H2S2O7 + H2O —> 2H2SO4
why is sulfer trioxide dissolved in concentrated sulphur dioxide instead of water?
As less heat is produced so it is safer and easier to manage
what are the three compromises of conditions to make sulfuric acid
fairly high temps , low pressure and vanadium pentoxide catalyst
what is the temp compromise for contact process
Low temperatures favour the forward reaction so more sulfer trioxide is produced and a compromise temp of 450 used however reducing the temperature can slow down a reaction so catalyst is used
pressure compromise for the contact process equation
higher pressure favour the forward reaction however increasing the pressure is expensive and the conditions already favour the forward reaction so it is usually carried out at just above atmospheric pressure
ammonium sulfate is a _________ made from _______ and ________
_____ and is used in agriculture to improve _____ yields and to make p____ , p________, d___ , d____________, f_______
fertiliser, ammonia, sulphuric acid, crop, paints, plastics, dyes, detergents, fibres
what does water of crystallisation mean
when there’s water in a lattice
what does a hydrated/anhydrous salt have
water crystallisation or not
what acid is good at removing water of crystallisation from hydrated salts such as ______ _________
concentrated sulfuric acid
copper (II) sulfate
What is the process of dehydration of hydrated copper sulphate?
when sulfiric acid is added to copper sulfate, it removes the crystallisation of water and turns the copper sulphate crystals into a anhydrous copper sulphate white powder which is very exothermic so lots of heat has given off
process of dehydration of sugars
When concentrated sulphuric acid is mixed in with sugar, it turns yellow then brown. It removes hydrogen and oxygen from the sugar forming water and solid carbon is left behind turning the solution black the water which is formed.
dilute the sulphuric acid and generates a lot of heat which causes the water producing steam which causes the carbon to rise out the beaker.
symbol equation for ammonia
NH3
symbol equation for sulfuric acid
H2SO4