SDG: TRXF b Flashcards

(80 cards)

1
Q

Overview

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2
Q

Qualitative analysis: Spectra interpretation

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3
Q

Principal peaks of X-ray Spectra according to Atomic Number Z

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4
Q

Step 1:

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5
Q

Step 2:

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6
Q

Step 3

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7
Q

Fingerprint analysis

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8
Q

Evaluating Spectra

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9
Q

K & L Spectral Peaks

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10
Q

Scatter

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11
Q

Rayleigh Scatter

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12
Q

Compton Scatter

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13
Q

Sum Peaks

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14
Q

Escape Peaks

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15
Q

Interferences

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16
Q

Spectral Interferences

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17
Q

Environmental Interferences

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18
Q

Results: peak separation

table

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19
Q

Results: peak separation

poor fitting

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20
Q

Quantitative analysis

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21
Q

Different elements = different sensitivities

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22
Q

Relative Sensitivity factors

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23
Q

Diagram of preparatory steps prior to TXRF analysis

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24
Q

Internal standardization vs. external standardization

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25
Some applications of TXRF
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Methods of sample preparation
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Sample preparation special support
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Sample preparation Spectra of a quartz
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Properties of sample carrier material
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Applications for TXRF analysis
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Water analysis
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Aerosol analysis definition
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Aerosol analysis origin
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Aerosol analysis climate
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1. Sampling procedure: impact of size of species
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Airborne particulates
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Plant material
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Vegetable and essential oils
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Medical and clinical applications
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Tissue samples
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High purity chemicals
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Other applications
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Silicon wafer analysis
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Direct TXRF - wafer mapping
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TXRF @ IMEC
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Monitoring of process equipment
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Contamination control: TXRF metrology
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The problem of Ruthenium
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A solution?
50
TXRF Instrumentation
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By adjustment monochromator
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Results: spectra
53
Evaluation performance
54
Detection limits for (T)XRF
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Detection limit
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Conditions and limitations
57
Pro and Con of TXRF benefits and drawbacks
58
Pro and Con of TXRF advantages and requirements
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Comparison of analysis techniques
60
Performance comparison
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Detection of light elements
62
Unified measurement angle
63
Vapor Phase Treatment (VPT) - TXRF
64
Pre concentration techniques
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Preconcentration: general concept
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Straight -TXRF
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The Principle of VPD-DC
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Vapor Phase Decomposition – Droplet Collection
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Preconcentration Efficiency (Ec )
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Impact of the VPD-DC Collection Chemistry
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The copper problem!
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Matrix effects
73
Conditions and limitations
74
Why SR-TXRF?
75
Brilliance
76
Bending magnet
77
Ultra-clean wafers
78
Wafer Mapping
79
Principles wafer mapping - TXRF
80
Examples WM-TXRF (2)