structure and bonding Flashcards

1
Q

What does bonding describe

A

how the outer electrons of atoms interact with each other

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2
Q

3 types of bonding

A

metallic, ionic, covalent

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3
Q

what does structure describe

A

the arrangement of the bonded atoms

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4
Q

2 types of structures

A

giant (lattice) – all metals and ionic, simple – gas or liquid

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5
Q

properties of metals x5

A

strong, high melting point, malleable, ductile, electric conductors

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6
Q

meaning of malleable and ductile

A

malleable – shaped when hit with hammer without breaking, ductile – stretched into wires/cables

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7
Q

how are metals held together?

A

electrostatic attraction between positive ions and delocalised electrons between them

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8
Q

what are alloys

A

mixtures of metals

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9
Q

properties of alloys x3

A

stronger, less malleable and less ductile

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10
Q

why are metals conductors of electricity

A

there are mobile delocalised electrons which carry charge

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11
Q

what is combined to form ionic compounds

A

metal and non-metal ( positive ion to a negative ion)

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12
Q

In an ionic compound, the _____ always transfers its outermost shell electrons to the _______

A

metal, non-metal

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13
Q

In ionic bonding, the metal gains/ loses the same number of electrons as its ____ _______

A

loses, group number

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14
Q

3 typical properties of ionic compounds

A

soluble in water, conducts electricity, high melting point

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15
Q

3 typical properties of covalent compounds

A

low melting point, electric insulator, insoluble in water

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16
Q

how are ionic compounds held together?

A

strong electrostatic forces of attraction between oppositely charged ions

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17
Q

why do ionic compounds have high melting points?

A

a lot of energy is required to overcome strong electrostatic forces of attraction

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18
Q

do ionic compounds conduct electricity

A

yes but only when molten

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19
Q

why do ionic compounds conduct electricity when molten/ in solution but not when solid

A

because ions are fixed in position when solid but are able to move in solution. Electrons can then flow through.

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20
Q

structure of ionic compounds

A

giant lattice

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21
Q

covalent bonding occurs between 2 or more ____________

A

non metals

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22
Q

each atom tries to achieve a _____ _______ _____ in covalent bonding

A

full outer shell

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23
Q

electrostatic attraction is between what and what in covalent bonding

A

positive nuclei and shared pair of electrons

24
Q

attraction forces between molecules are called

A

intermolecular forces

25
what is the spontaneous movement of a gas to fill its container called
diffusion
26
simple covalent bonds will not conduct electricity because
they don't have delocalized electrons or charged mobile ions
27
the strong covalent bonds do not break when liquid water boils into steam. What is broken then?
intermolecular forces
28
properties of simple covalent molecules x2
low boiling point b.c. of weak intermolecular forces, do not conduct electricity
29
examples of giant covalent structures
diamond, graphite
30
different structural forms of the same element are called
allotropes
31
in fullerenes, each carbon atom is _________ bonded to ______ other carbon stoms
covalently, 3
32
example of fullerene
C60 -- 60 carbon atoms
33
graphene is
a sheet of carbon atoms with no fixed formula
34
graphene is ____ atom thick
1
35
is graphene a good electrical conductor and why
yes, it allows free electrons to move across its surface ( each carbon atoms is only bonded to 3 other carbons )
36
is graphene strong or weak and why
covalent bonds make it extremely strong
37
giant molecular structures of carbon have high/low melting points because ...
high, many strong covalent bonds need to be broken
38
does graphite or diamond conduct electricity
graphite does, diamond doesn't
39
how does graphite conduct electricity
has 3 covalent bonds for each carbon atom --> not all its electrons are held in covalent bonds --> delocalized electrons are free to move and can carry an electrical current
40
uses of graphite x3
pencil, electrodes(conducts electricity but not very reactive), lubricant (layers can slide past each other)
41
what is an ore
a rock containing mental compounds with enough metal in it to make it worth extracting
42
what 3 metals are found pure in the ground (native)
gold, silver, platinum
43
zinc, iron, tin, lead and copper are extracted by...
reduction (smelting)
44
which 5 metals are extracted using electricity? what is the method called
potassium sodium calcium magnesium aluminium, electrolysis
45
what happens in a displacement reaction
a more reactive element takes the place of a less reactive one in a compound
46
is potassium or platinum more reactive
potassium
47
meaning of reduction
loss of oxygen
48
meaning of oxidized
gained oxygen
49
why can only some metals be extracted by reduction?
they have a lower reactivity than carbon, which is used to displace the metal
50
disadvantage of electrolysis
v. expensive as it requires lots of energy
51
meaning of electrolysis
using electricity to split a compound
52
2 methods of extraction for low grade ores
phytoextraction, bioleaching
53
briefly explain phytoextraction
plants absorb metal ions and concentrate these ions in their cells. The plants are burnt leaving plant ash, and the ash is processed using electrolysis or displacement to produce a metal
54
advantages of phytoextraction x2
conserves higher grade ores, reduces habitat destruction
55
disadvantages of phytoextraction x2
long process, costly labour time
56
briefly explain bioleaching
certain bacteria break down low grade ores to produce acidic solution ( leachate), metals can then be extracted by electrolysis or displacement
57
disadvantages of bioleaching
toxic products formed