Synthesis Flashcards

(49 cards)

1
Q

Alkane to halogenoalkane

A

X2 and uv light

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2
Q

Alkene to dihalogenoalkane

A

X2 and low temp

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3
Q

Alkene to diol

A

Acidified KMnO4

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4
Q

Alkene to alcohol

A

Steam, H3PO4 catalyst at high temp

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5
Q

Alkene to halognoalkane

A

HX

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6
Q

Alocohol to Ester

A

Carboxylate acid, acid catalyst, heat, or acyl chloride

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7
Q

Alcohol to aldehyde or ketone

A

K2cr2o7, H2SO4 reflux and heat or distil if aldehyde due to partial oxidation

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8
Q

Alcohol to alkene

A

Conc H3PO4

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9
Q

Alcohol to halogenoalkane

A

KBr 50 percent H2SO4
PCl5 or HCl
Red phosphorus, I2 reflux

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10
Q

Ester to alcohol

A

Dilute acid or alkali, reflux

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11
Q

Ester to carboxylic acid

A

Dilute acid or alkali reflux

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12
Q

Aldehyde or ketone to alcohol

A

LiAlH4

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13
Q

Aldehyde or ketone to hydroxynitrile

A

KCN and H plus, or HCN ethanol and reflux

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14
Q

Aldehyde and ketones to carboxulic acid

A

K2Cr2O7 acidified with reflex and eat

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15
Q

Carboxylic acid to acyl chloride

A

PCl5

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16
Q

Acyl chloride to amide

A

NH3 to make primary amide, or primary amine to make n substituted amide

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17
Q

Carboxylic acid to Ester

A

Alcohol, acid catalyst and heat

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18
Q

Nitrile to primary amine

A

LiAlH4 then dilute acid
Or
H2m nickel or platinum catalyst high temp and pressure

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19
Q

Nitrile to carboxylic acid

A

Dilute HCl reflux

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20
Q

Halogenoalkane to alkene

A

KOH ethanol and reflux

21
Q

Halogenoalkane to carboxylic acid

A

MGdry ether and reflux with CO2

22
Q

Carboxylic acid to alcohol

A

LiAlH4, gives primary alcohol

23
Q

Primary amine to amine

A

Halogenoalkane

24
Q

Halogenoalkane to nitrile

A

KCN, ethanol and reflux

25
Alkene to alkane
H2, nickel catalyst
26
Acyl chloride to carboxylic acid
Cold H2O
27
Acyl chloride to Ester
Alcohol
28
Halogenoalkane to primary amine
Excess ethanol ammonia and heat
29
Halogenoalkane to alcohol
Warm aqueous KOH reflux , or Mg dry ether and then a carbonyl then dilute acid
30
Nitrobenzene to phenylamine
Tin, conc HCl reflux then NaOH p
31
Benzene to nitrobenzene
Conc nitric acid and con sulfuric acid
32
Benzene to halobenzene
X2 halogen carrier
33
Benzene to phenylketone
Acyl chloride, AlCl3 as catalyst and reflux
34
Benzene to alkyl benzene
Halogenoalkane, AlCl3 catalyst relux
35
Phenol to 2,4,6 tribromophenol
Bromine water
36
Alcohol to alkene
Al2O3 dehydration
37
What reaction is halogenoalkane to alcohol or other way around
Nucleophilic substitutn
38
Alcohol to acyl hydrogensulfate
Water warm, hydrolysis
39
Carboxylic acid to acid anhydride
P2O5 distil
40
Acid anhydride to carboxylic acid
Water reflux in hydration
41
Grignard to carboxylic acid
CO2 and acid
42
Grignard to primary alcohol
Methanal and acid
43
Grignard to secondary alcohol
Other aldehyde and acid
44
Grignard to tertiary alcohol
Ketone and HCl
45
Benzene to bromobenzene
Fe filings and br2 | Febr3
46
Benzene to cyclohexane
H2 nickel catalyst
47
Methyl benzene to benzanoic acid
KMnO4 aqueous NaOH reflux
48
Benzene to methyl benzene
Ch3Cl AlCl3 and reflux
49
Benzene to phenol ethanone
Ch3COCl, AlCl3 catalyst and reflux