Textboolk LO1-3 Flashcards

1
Q

Quantization

A

Only certain energies are allowed

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2
Q

Principle quantum number (2)

A

A positive unit less integer
defines the energy of the allowed orbits in the H atom

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3
Q

The energy of the electron in an orbit has a negative value because

A

the electron in the atom has a lower energy than when it is free.

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4
Q

The 0 of energy occurs when

A

n= infinity
That is when the election is infinitely separated from the nucleus

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5
Q

Ground state

A

An atom with its electron in the lowest possible energy levels

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6
Q

The energy of the electron depends on

A

n

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7
Q

The larger the value of n, (radius and energy negativity)

A

The larger the Bohr radius and the less negative the value of the energy

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8
Q

The difference between successive energy levels becomes _________ because

A

smaller as n becomes larger

Energy is dependent on 1/n^2

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9
Q

what needs to happen when an electron goes From n=1 to n=2 electron state

A

Energy is absorbed from the surroundings

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10
Q

A consequence or requirement of quantization (2)

A

A specific and precise amount of energy

No more or no less

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11
Q

When a electron falls down its energy level to a diff one

A

Since only certain energy levels are possible, only photons with particular energies and wavelengths are emitted

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12
Q

principle quantum number (3)

A

any integer from 1-infinity

primary factor in determining the energy of an orbital
defines size of an orbital

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13
Q

In atoms having more than 1 electron, two or more electrons may have the same n value. They are said to be

A

in the same electron shell

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14
Q

orbital example

A

3px

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15
Q

which quantum number or combination is needed to specify a given subshell in an atom?

A

n and l

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16
Q

repulsion counteract the nuclear attraction making electrons

A

easier to remove by helping to push it away

17
Q

shielding reduces the full nuclear charge to

A

an effective nuclear charge

18
Q

the energy difference arises from three factors

A

nuclear attractions, electron repulsion and orbital shape

19
Q

puli exclusion principle

A

requires each electron to have a unique set of four quantum number

20
Q

repulsion shield electrons from the ______ reducing it to an_____

A

the full nuclear charge

effective nuclear charge

21
Q

aufbau principle

A

we start at the beginning of the periodic table and add one proton to the nucleus and one electron to the lowest energy sub level available.

22
Q

order for filling energy sub levels

A

1s, 2s, 2p,3s,3p,4s,3d,4p,5s,4d,5p

23
Q

Hunds rule

A

No electrons are paired in a set of orbitals of equal energy until every orbital in the set has one electron.

24
Q

formula for which orbital filled first

A

n+l

Whichever orbital has the lower n+1 value will fill first

25
formula for maximum electron possible for nth shell
2n^2
26
the energy gaps between sub shells of a given shell becomes______ as n _____
smaller increase
27
The electrons included in the noble gas notation are often referred to as
core electrons
28
What are the two exceptions for transition metals and draw it out
29
Transition metal steps or exceptions for electron configs
Make sure that d orbital is half filled (5) or fully filled (10) by promoting electrons from the 4s
30
from Scandium and onwards, the 3d orbital of transition metals actually becomes
lower in energy than the 4s, which is why we write 3d before 4s in the configuration.