The atmosphere Flashcards
(19 cards)
Troposphere (general)
15km: N2, O2, CO2, Ar, H20: molecules & breathing
Stratosphere (general)
50km: N2, O2, O3: ozone
Mesosphere (general)
85km: N2, O2, N2+, O2+, NO, NO+: meteor
Thermosphere (general)
600km: N2, O2, N2+, O2+, N+, O+, NO+, N, O: satellite, shuttle, space station, northern lights
At high altitudes N2 and O2 are subject to
high energy and UV light
Dissociation in Thermosphere reactivity involves:
Breaking O2 bonds with <240nm and breaking N2 bonds with <126nm
Ionization in Thermosphere reactivity involves:
taking Os and deionizing one (Os = <91nm & Ns = <80nm) with 1310KJ/mols remaining
Photochemical Rxn:
It is when a reaction takes a substance into an excited states to help processes occur
Free Radicals in Upper atmosphere help with:
Reactions
How are radicals made?
By the photochemical reactions
Free Radicals - Abstract
The radical attacks the H atom and cleaves it form a molecule
Free Radicals - Fragment
The radical will attack it’s own bond and cleave itself from the molecule
Free Radicals - Multiple Bonds
The Radical will cleave a double bonded atom and attach itself to the molecule
Free Radicals - Recombine/Coupling
Two radicals reacting and combining to create a fully formed molecule
4 steps of a Hydroxy Radical
- Photochemical: making radical
- Making Ozone: O radical + O2
- Excited State: Adding UV/light
- Radical Formation: Remake initial Radical
Chapman Cycle describes:
The formation and destruction of Ozone
Chapman Cycle steps:
- Cleave O2 with light to make radical
- Add radical to O2 to make ozone
- (maybe) add UV to O3 to get a radical again
- (maybe) add a radical to get O2 again
Zig Zag effect
Effect describing the temperature of the atmospheric layers in relation to UV light and radiation
Zig Zag effect from highest altitude to lowest
- more ions at higher altitudes = more kinetic energy = more absorption
- longer wavelength absorption = higher temps
- UV range decreases in lower altitudes = lower temps
- radiation hits the earth and bounces back as IR-Radiation or CO2