The Periodic Table Flashcards
(30 cards)
What are the rows called?
periods
What are the columns called?
groups
What are A elements and where are the valence e-?
aka “representative elements” and include groups IA thorough VIIIA, valence electrons in the s or p subshells
What are B elements and where are the valence e-?
aka “nonrepresentative elements”, include transition elements (valence e- in the s and d subshells), lanthanide and actinide series (valence e- in s and f subshells)
Metals
lustrous (shiny) solids, generally high melting points, can be deformed without breaking (malleability/ductility), low electronegativity, large atomic radius, small ionic radius, low ionization energy, and low electron affinity. Found on the left side of the periodic table.
What are oxidation states?
charges when forming bonds with other atoms or “different possible charged forms” ex: Cu+2
What makes something a good conductor?
When the valence electrons are only help loosely so they are free to move around
Nonmetals
brittle in solid state, no/little luster, high ionization energies, electron affinities, electronegativities, small atomic radii and large ionic radii, poor conductors in heat, inability to easily give up electrons, less unified in their chemical and physical properties, found in the upper right side of the periodic table
Metalloids
aka “semimetals”, physical properties vary widely, combinations of nonmetals and metals, found in stair step group of elements
Effective Nuclear Charge (Zeff)
a measure of the net positive charge experienced by the outermost electrons, attraction between the valence shell electrons and the nucleus, increases right to left across table, constant down groups
What is the electrostatic trend?
as you move down a group, electrostatic attraction decreases
Octet rule
elements gain or lose electrons to try and achieve a stable octet of valence electrons; many exceptions
Atomic radius
is equal to one-half of the distance between the centers of two atoms of an element that are briefly in contact with each other, decreases right to left across table, increases down groups
Ionic radii
In order to understand know that: (1) metals lose electrons and become positive, while nonmetals gain electrons and become negative (2) metalloids can go either direction Metals - smaller ionic radius Nonmetals - larger ionic radius
Ionization energy (IE)/ ionization potential
energy required to remove an electron from a gaseous species, increases left to right and bottom to top
Endothermic process
removing an electron which requires INPUT of heat
Exothermic process
requires an electron which OUTPUTs energy as heat
Relationship between Zeff and ionization energy
the higher the atoms Zeff, the higher the ionization energy. this is because Zeff is a measure of how close the valence electrons are being held to the nucleus (higher = closer) and so this makes it hard to remove requiring more energy (higher ionization energy)
What is first ionization energy?
the energy required to remove the first electron
Active metals
have extremely low ionization energies so much that they are almost always found naturally in ionic compounds instead of neutral forms, ex: Li and Be
Electron affinity
basically how likely an element is to attract electrons to complete it’s octet but the actual definition is the energy dissipated by a gaseous species when it gains an electron, decreases top to bottom, increase left to right, “opposite of ionization energy”
Relationship between Zeff and electron affinity
as Zeff increases, so does electron affinity. This is because the stronger the electrostatic pull the greater the energy release when an atom gains an electron
Electronegativity
measure of the attractive force that an atom with exert on an electron in a chemical bond
Relationship between electronegativity and ionization energy
the lower the ionization energy, the lower the electronegativity