Thermochemistry Flashcards

1
Q

What is thermochemistry

A

The study of relations between CHEMICAL REACTIONS and ENERGY

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is MATTER

A

Anything having a MASS and occupying SPACE

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How is MATTER classified

A

by its STATE (liquid, solid, gas) and its COMPOSITION (heterogeneous mixture, element, compound, etc.)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What is ENERGY

A

WORK of anything that can be produced by or converted into WORK

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What are the two classifications of ENERGY

A

POTENTIAL and KINETIC

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is the formula for POTENTIAL ENERGY?

A

E(p) = mg(delta)h

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the formula for KINETIC ENERGY?

A

E(k) = [mv^2]/2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What do E, v, m, g and h stand for?

A

E= energy, v=, m=, g=, h=.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

How many JOULES is one CALORIE?

A

1CALORIE = 4.184 JOULES

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What is the formula for ONE JOULE

A

kg*m^2/s^2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What are the forms of POTENTIAL ENERGY? (4)

A

Gravitational, Chemical, Nuclear, Electrical

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What are the forms of KINETIC ENERGY? (2)

A

Motion, heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is the relation between a SYSTEM, a BOUNDARY and SURROUNDINGS?

A

the SYSTEM is limited by the BOUNDARY. Outside of the BOUNDARY, there are SURROUNDINGS.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is an OPEN SYSTEM?

A

A SYSTEM that may exchange ENERGY and MATTER with SURROUNDINGS

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is a CLOSED SYSTEM?

A

A SYSTEM that may NOT exchange MATTER ONLY with SURROUNDINGS

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is an ADIABATIC SYSTEM?

A

A SYSTEM that may not exchange HEAT ONLY with SURROUNDINGS

17
Q

What is an ISOLATED SYSTEM?

A

A SYSTEM that an not exchange HEAT nor MATTER with surroundings.

18
Q

What is an ENDOTHERMIC PROCESS?

A

When there is ABSORPTION of ENERGY

19
Q

What is an EXOTHERMIC PROCESS?

A

When there is a RELEASE of ENERGY

20
Q

What is the formula for ENTHALPY?

A

(Delta)H = q(p)

21
Q

What do q and p stand for?

A

q = enthalpy (J/mol or kJ/mol) and p = constant pressure

22
Q

What INSTRUMENT is used to measure HEAT?

A

A CALORIMETER

23
Q

What is CALORIMETRY

A

The measurement of HEAT FLOW

24
Q

What is the sum of q’s always equal to?

25
What system is a CALORIMETER and its CONTENTS?
An ADIABATIC SYSTEM
26
What is HEAT CAPACITY?
The amount of HEAT required to raise TEMPERATURE of a substance by 1K or 1C
27
What is the formula for HEAT CAPACITY?
C = q/(delta)T
28
What is the difference between HEAT CAPACITY and SPECIFIC HEAT CAPACITY?
SPECIFIC HEAT CAPACITY is for a SPECIFIC AMOUNT (g) of substance while HEAT CAPACITY is for an OBJECT
29
What is the formula for SPECIFIC HEAT CAPACITY?
C = q/w(delta)T, w meaning weight (g)
30
What is the standard enthalpy of formation of a compound?
The ENTHALPY CHANGE after the formation of 1 MOLE at 25C and 1 ATM from the elements in their standard state.
31
What is the law of Lavoisier and Laplace
If we switch the sides of an equation, the enthalpy becomes the opposite sign.
32
What is the enthalpy change for a chemical reaction ?
q = n(delta)h, n meaning number of moles.
33
What is the delta H of any element equal to ?
Zero.