THERMOCHEMISTRY Flashcards

(41 cards)

1
Q

the study of energy or heat flow that accompanies a chemical reaction and/or physical transformations.

A

Thermochemistry

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2
Q

a branch of thermodynamics that deals with the interconversion of energy between 2 forms:

A

heat and work

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3
Q

Capacity to do work or to produce heat

A

energy

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4
Q

a branch of thermodynamics that deals with the interconversion of energy between 2 forms:

A

heat and work

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5
Q

energy can be converted from one form to another but can be neither created nor destroyed.

A

law of conservation of energy

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6
Q

The total energy content of the universe is constant.

A

true

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7
Q

energy due to position or composition

A

potential energy

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8
Q

involves the transfer of energy between two objects due to a temperature difference.

A

heat

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9
Q

force acting over a distance

A

work

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10
Q

Energy is a state function; work and heat are not State Function

A

true

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11
Q

energy due to motion of the object and depends on the mass of the object and its velocity

A

kinetic energy

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12
Q

property that does not depend in any way on the system’s past or future (only depends on present state).

A

state function

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13
Q

is a form of energy transfer between two objects as a result of their difference in temperature

A

heat

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14
Q

is the part of the universe being studied or to which attention is focused.

A

system

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15
Q

include everything else in the universe.

A

surroundings

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16
Q

part of the universe in which we focus our attention (the reaction)

A

system

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17
Q

anything that is not the system (the beaker, our hands, a solvent, a thermometer, etc.)

18
Q

can exchange matter, can exchange heat energy

19
Q

no exchange of matter, can exchange heat energy

A

closed system

20
Q

can exchange matter, can exchange heat energy

21
Q

no exchange of matter

A

isolated system

22
Q

Heat flow is into a system.
Absorb energy from the surroundings.

A

endothermic reaction

23
Q

Energy flows out of the system.

Energy gained by the surroundings must be equal to the energy lost by the system.

A

exothermic reaction

24
The study of energy and its interconversions
thermodynamics
25
26
no exchange of matter
isolated system
27
Law of conservation of energy is often called the…
first law of thermodynamics
28
states that heat is a form of energy, and thermodynamic processes are therefore subject to the principle of conservation of energy. This means that heat energy cannot be created nor destroyed
first law of thermodynamics
29
thermodynamic quantities consist of two parts: Number gives the magnitude of the change. Sign indicates the direction of the flow
internal energy
30
E of a system is the sum of the kinetic and potential energies of all the “particles” in the system
internal energy
31
There are two possible types of transformation that a system may undergo:
a. A physical change, i.e a change in physical state that involves release or absorption of energy. b. A chemical change, i.e a chemical reaction that is accompanied by a gain or loss of energy.
32
E of a system is the sum of the kinetic and potential energies of all the “particles” in the system
internal energy
33
Science of measuring heat
calorimetry
34
The energy required to raise the temperature of one gram of a substance by one degree Celsius.
specific heat capacity
35
The energy required to raise the temperature of one mole of substance by one degree Celsius.
molar heat capacity
35
The energy required to raise the temperature of one gram of a substance by one degree Celsius
specific heat capacity
36
If two reactants at the same are mixed and the resulting solution gets warmer, this means the reaction taking place is EXOTHERMIC. An ENDOTHERMIC reaction cools the solution.
true
37
the amount of heat absorbed or released by a chemical reaction at constant atmospheric pressure.
enthalpy
38
This states that the total enthalpy change during the complete course of a chemical reaction is the same whether the reaction is made in one step or in several steps.
hess’s law
39
is a relationship in physical chemistry named after Germain Henri Hess, a Switzerland-born Russian chemist and physician who published it in 1840.
hess’s law of constant heat summation