Thermodynamics (4) Flashcards

(11 cards)

1
Q

why do substances with high chemical potential spontaneousy change ?

A
  1. high enthalpy thefore have large capcaity to do work by warming the surroundings
  2. ….as a result they have low enthalpy thefore it has large capacity to do work by gainign entropy during reactions were entropy increases
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2
Q

what does chemical potentila measure ?

A

the capacity of a system to do useful work

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3
Q

whta is free energy ?

A

what remains of chemical potential after bring used up in a system

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4
Q

what is chemical potential called at constant pressure ?

A

Gibbs free energy
(G)

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5
Q

substances with high free energy….

A

have high enthalpy (lots to loose)
and
high entropy (lots to gain)

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6
Q

Gibbs free energy
equation

A

G= H - TS

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7
Q

how much useful energy is produced at high temperatures and why?

A

there is less useful work because heat is a chaotic form of energy

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8
Q

how do you predict spontaneous reaction ?

A

when G is less than 0

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9
Q

what is temperature measured in in free energy

A

in kelvin = C+273

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10
Q

what is enthalpy measured in ?

A

kJ mole-1

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11
Q

what is entropy measured in ?

A

J K-1 mole-1
be mindful of KILO

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