Topic Science assess Flashcards
(22 cards)
Electrons prefer to occupy degerate orbitals and have parallel spins
Hund’s rule
Mass # of a neutra element =
of protons + neutrons
Trend of electronegativity in the periodic table
Increases up and right
Electron affinity =
The amount of energy released when a gaseous atom or ion gains an electron
Which decreases from left to right across a period?
Electronegativity, atomic radius, electron affinity, or ionization energy?
Atomic radius
Order the following in increasing intermolecular bond strength:
Hydrogen bonding, dispersion forces, dipole-dipole interaction
Dispersion forces < Dipole-dipole interaction < Hydrogen bonding
Molecular geometry of boron trifluoride (BF3)?
Trigonal planar
Type of reaction for:
CaCl2(aq) + 2 AgNO3 (aq) -> Ca(NO3)2 (aq) + 2 AgCl(s)
Metathesis
Things that affect reaction rates
Increase temp, lower Ea, incrase reactant collision frequency
The only physical factor that can change the value of the Keq is…
Temperature
What’s the Equation for Gibbs free energy?
∆G˚ = ∆H˚– T∆S˚
Kinetic molecular theory of gases equation(s)
KE = (3/2)kT
KE = (1/2)mv2
Boyle’s Law
P1V1 = P2V2
What is the concentration of Ag+ in a saturated solution fo AgCl @ 25˚C (Ksp of AgCl = 1.8 x10-10)
1.34x10-5 M
A scientists wants to prepare a 50 mM solution of NaOH. if he starts out with 60 mL of 0.3 M NaOH and adds pure water until reachign teh desired concentration, how much water will he have added?
300 mL
What’s the relationship between pH and hydrogen ion concentration?
pH = -log[H+]
i.e. if [H+] = 10-6 then pH is 6
As NAD+ is converted into NADH during fermentation, it is acting as a …
oxidizing agent
For sodium carbonate, what are it’s oxidation #s?
Sodium carbonate = Na2CO3
Na = +1
C = +4
O = -2
In a galvanic cell, ____ occurs at the anode, ____ occurs at the cathode, and the reaction is (spontaneous/nonspontaneous)
Oxidation occurs at the anode.
Reduciton occurs at teh cathode.
Reaction is spontaneous
Galvanic cell is defined as a (+/-) EMF which means that the reaction is (spontaneous/nonspontaneous)
Galvanic cell = +EMF
Rxn is spontaneous
Relationship between acid dissocaiton constants and sterngth? (in terms of Ka and pKa)
A strong acid will ahve the highest Ka and lowest pKa
Charles’ Law
V1/T1 = V2/T2