transition metals Flashcards
(17 cards)
if there a no ligands what does this mean?
colourless
what does Fe2+ form in solution and what colour?
[Fe(H2O)6]2+
PALE GREEN
what does Fe3+ form in solution and what colour?
[Fe(H2O)6]3+
YELLOW
Cu2+
BLUE
Cr3+
DARK GREEN
Co2+
PINK
PALE GREEN COMPLEX
Fe2+
BLUE COMPLEX
Cu2+
YELLOW COMPLEX
Fe3+
PINK COMPLEX
Co2+
DARK GREEN COMPLEX
Cr3+
WHen there are 6 ligands whats the shape
octahedral
4 ligand shape is
tetrahedral
When OH- is added to [Cr(H2O)6]3+ what is formed, and what happens when excess OH- is added?
Grey-Green precipitate of [Cr(H2O)3(OH)3]
On excess the precipitate dissolves giving a deep green solution of [Cr(OH)6]3-
When OH- is added to [Fe(H2O)6]2+ what is formed, and what happens when excess OH- is added?
Dark green precipitate of [Fe(H2O)4(OH)2]
On excess no further reaction for bulk
When OH- is added to [Fe(H2O)6]3+ what is formed, and what happens when excess OH- is added?
Red-Brown precipitate of [Fe(H20)3(OH)3]
No further reaction with excess
When OH- is added to [Cu(H2O)6]2+ what is formed, and what happens when excess OH- is added?
Pale blue precipitate of [Cu(H2O)4(OH)2]
no further reaction with excess