Unit 1 Topic 1 PT and Trends Flashcards
(25 cards)
What is an atom
An atom is the smallest unit of matter and they are composed of three subatomic particles
Outline the 3 subatomic particles, their charges, masses and locations
Proton
- positively charged
- 1
-found in the nucleus
Neutron
- neutral charge
- 1
- found in the nucleus
Electron
- negatively charged
- 1/1800
- found in the shells that surround the nucleus that are held by electrostatic attraction
What is an ion
Ions are atoms that have lost or gained electrons and therefore result in an unbalanced charge that is either positve or negative
Cation
Cations are positive ions that have lost an electron meaning there is more protons than electrons and therefore a positive charge
Anions
Anions are negative ions that have gained an electron meaning there is more electrons than protons and therefore a negative charge
What are Features of the periodic Table
-Each row is called a period and outline how many shells will make up the electron configurations in the said atom
-A column is known as a group and dictates the number of valence electrons that will be present in the electron configuration
What does the Bohr Model propose
- proposes that electrons reside in shells
- such shells are arranged that each shell gets progressively further away from the nucleus than the previous
- The number of electrons present in each shell is dictated by the rule 2n^2
- proves that the atom is mostly empty space with a positive charge near the centre as concluded by the rutherford gold foil experiment
What are the subshells for electronic configuration and where are they located on the periodic table
S- groups 1 and 2
P- groups 13-18
D- groups 3-12
Orbital
The physical regions occupied by the electrons
- max number of two electrons per orbital
- the orbitals and subshells are filled in increasing energy levels
What happens when electrons are heated
-Electrons when exposed to heat gain energy
-This causes atoms to be in a state known as the excited state
-This is where the atoms is very volatile and spontaneous
-The electrons in the atoms electron configuration will jump to higher energy levels as the electrons have absorbed energy from the heat
-The electrons that have been excited will then drop to ground state releasing the energy they have absorbed as a form of electromagnetic radiation present in the form of light
Electronic configuration of copper
1s2 2s2 2p6 3s2 3p6 3d10 4s1
Electronic Configuration of chromium
1s2 2s2 2p6 3s2 3p6 3d5 4s1
Electron Configuration of Krypton
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
Discuss the energy levels in the 3rd and 4th energy levels
The 4s subshell is of lower energy than the 3d subshell. Thereofre for elements past calcium fill 3p6, leave a gap, write 4s2 and then come back and place electrons in the 3d subshell
Define Core charge
Core charge is the attraction of valence electrons have to the nucleus as opposite charges attract
- it is equal to the number of valence electrons in an atom
Trends of Core charge
Increases across a period due to the nucleus being more positive, meaning the valence electrons is more strongly attracted to the nucelus
Remains the same down a group as number of valence electrons remains the same
Define shielding effect
Refers to how great of a shield the valence electrons have from the nucleus
- is equal to the number of inner shell electrons
trends of shielding effect
Across a period shielding effect is constant as there is no new shell with electrons that is added but the nucleus becomes more positive and therefore the valence electrons are more strongly attracted to the nucleus
Down a group shielding effect increases as number of inner shells increases and therefore the valence electrons are less strongly attracted to the nucleus as they are further away
Atomic Radius
Distance between the nucleus and the valence electrons
Trends of Atomic radius
Across a period as the core charge increases and shielding effect is kept constant therefore the valence electrons are more strongly attracted to the nucleus hence decreasing the atomic radius
Down a group atomic radius increases as there is an increased number of occupied electron shells
Electronegativity
The ability of an atom to attract other atom’s valence electroms to itself
Trends of Electronegativity
Across a period core charge increases with a constant shielding effect and therefore the nucleus is more attracted to any valence electrons and thus higher electronegativity
Down a group electronegativity decreases as valence electrons are less strongly attracted to the nucleus as they are further away as the atomic radius increases and an increased shielding effecr
First ionisation energy
the energy required to remove one electron from valence shell in a gaseous atom
Trends of first ionisation energy
Across a period first ionisation energy increases as core charge increases, therefore the valence electrons are more strongly attracted to the nucleus so they require more energy to remove
Down a group first ionisation energy decreases as the valence electrons are less attracted to the nucleus, therefore it is easier to remove as the valence shell is further from the nucleus meaning there is a greater shielding effect on the valence electrons