unit 1a: atomic orbitals and quantum numbers Flashcards

(27 cards)

1
Q

quanta

A

the fixed amount of energy possessed by electrons within atoms

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2
Q

electrons behave as

A

standing (stationary) waves in an atom

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3
Q

standing waves

A

vibrate in time but do not move in space

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4
Q

different sizes and shapes of standing wave

A

these are possible around the nucleus of an atom and are known as orbitals

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5
Q

orbitals

A

an area of space where there is a high probability of finding an electron

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6
Q

maximum capacity of an orbital

A

2 electrons

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7
Q

quantum numbers

A

define the energy of an electron and give information about its location within an atom

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8
Q

principle quantum number

A

n

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9
Q

n

A

describes the energy levels an electron is found in and is related to orbital size

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10
Q

possible values of n

A

n= 1,2,3 (1st shell, 2nd shell, 3rd shell)

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11
Q

angular momentum quantum number

A

l

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12
Q

l

A

describes the shape of the subshell / orbital

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13
Q

possible values of l

A

l=0 —> n-1

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14
Q

different shapes of orbitals are identified as

A

s(l=0) , p(l=1) , d(l=2) , f(l=3)

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15
Q

s orbital shape

A

spherical l=0

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16
Q

p orbital shape

17
Q

d orbital shape

A

double dumbbell l=2

18
Q

magnetic quantum number

19
Q

ml

A

describes the orientation in space time of the orbital

20
Q

possible values of ml

21
Q

orbitals increase in energy from

A

s > p > d > f

22
Q

degenerate

A

equal in energy

23
Q

orbitals within a subshell (i.e. the same shape) are

24
Q

spin magnetic quantum number

25
ms
describes the direction of electron spin
26
spins in orbitals
two electrons in the same orbital must have opposite spins
27
possible values of ms
+1/2 , -1/2