Unit 2 Flashcards

(45 cards)

1
Q

metabolism

A

sum of all chemical reactions that occur in the cell

anabolism + catabolism

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2
Q

metabolic pathway

A

a sequential series of chemical reactions in living cells; each reaction is catalyzed by a unique enzyme

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3
Q

anabolism

A

process of using energy to build large molecules from smaller molecules
ex. photosynthesis, synthesis of macromolecules

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4
Q

catabolism

A

process of breaking down compounds into smaller molecules to release energy
ex. cellular respiration

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5
Q

energy

A

the ability to do work

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6
Q

kinetic energy vs potential energy

A

energy of motion vs stored energy

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7
Q

when energy is transferred from one place to another, that is called _____

A

work

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8
Q

1st law of thermodynamics

A

energy cannot be created or destroyed, but it can be transformed from one type into another and transferred from one object to another

all energy is accounted for

energy cannot be lost or disappear

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9
Q

chemical energy

A

potential energy stored in the arrangement of the bonds in a compound

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10
Q

bond energy

A

measure of the strength or stability of a covalent bond
equal to the minimum amount of energy required to break a particular type of bond
equal to the amount of energy released per mole when a bond is formed

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11
Q

why do free, unbonded atoms have more chemical energy than any compound

A

because energy is always released when a bond forms

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12
Q

2nd law of thermodynamics

A

the law of entropy
the entropy of the universe increases with any change that occurs
in every energy transfer or conversion, some of the useful energy in the system becomes unavailable to do work

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13
Q

entropy

A

measure of disorder

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14
Q

free energy

A

energy transformations are never 100% efficient. some energy is always lost to the environment, which leads to an increase in entropy.
energy that is not lost, or the portion left that is available to do (useful) work in the given system is free energy.

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15
Q

how are changes in free energy produced

A

chemical reactions break some bonds and form new ones in products

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16
Q

exergonic reactions

A

chemical reaction that releases energy
spontaneous and involves a decrease in free energy
products of reaction contain less free energy than reactants (delta G is negative)

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17
Q

endergonic reactions

A

chemical reaction that requires energy
not spontaneous, and involves an increase in free energy, gains free energy
products of reaction contain more free energy than reactants (delta G is positive)

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18
Q

adenosine triphosphate (ATP)

A

adenine, phosphate, 3 phosphate groups
last phosphate is unstable
large quantity of energy is released when ATP becomes ADP plus inorganic phosphate P

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19
Q

redox reactions, electron transfers

A

transfer of electrons/ redox reactions during chemical reactions releases energy stored in organic molecules which is used to synthesize ATP

20
Q

oxidation vs reduction

A

loss of electrons from one substance vs addition of electrons to another substance

21
Q

the ______ form of a molecule is always at a higher energy level than the _________ form
and why

A

reduced, oxidized

because electrons that pass from one atom to another carry energy with them

22
Q

electron carriers

A

compounds that pick up electrons from energy-rich compounds and then donate them to low-energy compounds
an electron carrier is recycled

23
Q

all organisms require energy for

A
active transport
cell division
movement
production of biomolecules
reproduction
temperature regulation
24
Q

how does ATP store energy

A

a lot of stored energy in each bond

bonding of negative P groups is unstable > spring loaded > P groups “pop off” easily & release energy

25
why is ATP unstoreable
too reactive transfers P too easily only short term storage
26
digest organic molecules to get...
raw materials for synthesis | fuels for energy
27
how do we harvest energy from fuels
digest large molecules into smaller ones break bonds and move electrons from one molecule to another as electrons move they “carry energy” with them that energy is stored in another bond, released as heat or harvested to make ATP
28
how do we move electrons in biology
electrons cannot move alone in cells | they move as part of an H atom
29
oxidation and reduction in terms of energy
oxidation - exergonic, releases energy | reduction - endergonic, stores energy
30
cellular respiration
The process by which mitochondria break down glucose to make ATP two types: aerobic and anaerobic
31
aerobic respiration
requires oxygen and carried out by plants, animals, and some bacteria
32
anaerobic respiration
requires no oxygen and carried out by yeast, some bacteria, and sometimes animals
33
3 overall goals of cellular respiration
-to break the bonds between glucose to result in carbon dioxide (producing 6 CO2) -to move H atom electrons from glucose to oxygen to form water (producing 6 H2Os) -to trap as much free energy as possible released in the form of ATP (ultimate goal) accomplished through substrate-level phosphorylation and oxidative phosphorylation
34
substrate-level phosphorylation
ATP is formed directly in an enzyme-catalyzed reaction a phosphate-containing compound (PEP or GDP) transfers a phosphate group directly to ADP, forming ATP This type of energy transfer occurs in glycolysis and in the Krebs cycle
35
oxidative phosphorylation
ATP is formed indirectly involves sequential redox reaction, with oxygen being the final electron acceptor More complex Yields more ATP than substrate-level phosphorlation
36
cellular respiration stages and changes
Stage 1: Glycolysis – a 10 step process occurring in the cy p to lasm Stage 2: Pyruvate Oxidation – a one-step process in the mitochondrial matrix Stage 3: The Krebs cycle – an 8 step cyclical process in the mitochondrial matrix Stage 4: Electron transport and chemiosmosis – a multistep process in the mitochondrial cristae
37
The ETC consists of:
4 protein complexes: NADH dehydrogenase complex, complex II, cytochrome bc complex, cytochrome c oxidase complex 2 mobile electron carriers: ubiquinone/coenzyme Q, cytochrome C
38
ATP synthase
protons enter the matrix through proton channels associated with ATP synthase (ATPase) for every H+ that passes through, enough free energy is released to create 1 ATP from the phosphorylation of ADP
39
chemiosmosis
a process that uses energy in a hydrogen ion gradient across the inner mitochondrial membrane to drive phosphorylation of ADP to form ATP
40
regulation of aerobic respiration
feedback inhibition
41
speeding up aerobic respiration
high levels of ADP low levels of citrate both act on phosphofructokinase (PFK)
42
slow down aerobic respiration
``` excess ATP (acts on PFK) accumulation of citrate (acts on PFK) excess NADH (acts on pyruvate dehydrogenase) ```
43
lipid catabolism
2nd energy source triglycerides are digested into fatty acids and glycerol glycerol can be converted to G3P (glyceraldehyde-3-phosphate) and enter glycolysis fatty acids undergo beta oxidation (same process as pyruvate oxidation) and enter Krebs cycle
44
protein catabolism
first go through deamination where amino groups are removed and converted to ammonia waste product amino acids are oxidized and can enter as pyruvate, acetyl units, or molecules in Krebs cycle
45
total yield of ATP from cellular respiration
2 ATP from glycolysis 2 ATP from krebs cycle 4 ATP from NADH formed during glycolysis 6 ATP from NADH formed during pyruvate oxidation 22 ATP from NADH and FADH2 formed during Krebs cycle total of 36