Unit 2 | Topics: Strength of Acids and Bases, properties of salts, dissociation, polyprotic, leveling effect Flashcards
(8 cards)
Comparing Acids
by Ka or pKa, the one higher is the stronger acid
strong acids
perchloric - HClO4
nitric - HNO3
sulfuric - H2SO4
HI, HBr, HCl
Strong bases
LiOH
NaOH
KOH
Ca(OH)2
Sr(OH)2
Ba(OH)2
Case 1: Salts that yield neutral solutions
If both ions are conjugate to a stronge acid or a strong base, then both ions show noa cid-base properties. Ions remain as ions in solution, result in neutral pH
Case 2: Salts that yield weak acidic/basic solutions
If one ion has very weak properties, ie conjugate to a strong acid or a strong base, the other ion is a weak acid or base, then only the weak species is active and determines pH
Case 3: Salts that are both weak acid and bases
if both ions are weak acid/ base, the pH is determined by the species with largest equilibirum constant. determine the acid and base, compare calculated Ka and Kb respectively
weak acid/ base dissociation
- compare K values to determine the dominant source of H3O+/ OH
- make ICE table for dominant rxn
- solve like a small K and do approximations
percent dissociated
amount dissociated/ inital amount x 100