unit 7 Flashcards

(43 cards)

1
Q

kinetic molecular theory (kmt)

A

describes the behavior of matter in terms of particles in potion, it makes assumptions about the size, motion, and energy of gas particles

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2
Q

kmt - particle size and attractive forces

A

small particles, little to no attraction

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3
Q

kmt - particle motion

A

constant and random motion in a straight line

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4
Q

kinetic energy of a particle

A

1/2 mv^2

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5
Q

how does kmt explain gas expanding or contracting

A

when the volume of a container increases, particles fill that space

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6
Q

diffusion

A

the movement of one material through another

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7
Q

kmt diffusion

A

particles can easily flow because there is no attraction

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8
Q

effusion

A

diffusion through a tiny opening

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9
Q

what effuses faster

A

lighter gasses effuse faster

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10
Q

grahams law of effusion

A

rate of effusion is inversely proportional to the square root of its molar mass

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11
Q

pressure

A

when particles collide with the walls of their containers

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12
Q

used to measure atmospheric pressure

A

barometer

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13
Q

used to measure pressure of a gas

A

manometer

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14
Q

ideal gas

A

a gas where its particles take up no space

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15
Q

ideal gas properties

A

-no imf attraction forces
-not attracted to or repelled by the walls of the container
-constant random motion in straight lines
-perfectly elastic
-follows gas laws

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16
Q

when do real gasses act most like ideal gasses

A

at high temps and low pressures

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17
Q

what types of gas particles deviate most from ideal gas behavior

A

large gas particles

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18
Q

intramolecular forces

A

forces inside a molecule

19
Q

intermolecular forces

A

forces between molecules

20
Q

solid to liquid

A

melting, energy and distance up, imfs down

21
Q

liquid to solid

A

freezing, energy and distance down, imfs up

22
Q

liquid to gas

A

boiling / vaporation, energy and distance up, imfs down

23
Q

gas to liquid

A

condensation, energy and distance down, imfs up

24
Q

solid to gas

A

sublimation, energy and distance up, imfs down

25
gas to solid
deposition, energy and distance down, imfs up
26
volatile liquids
evaporate easy, low imfs - gasoline, perfume - high pressure
27
non volatile liquids
do not evaporate easy, high imfs - water - strong imfs have a lower equilibrium vapor pressure because when imfs are strong its difficult for molecules to enter a gas phase, so there are fewer molecules of gas and less pressure
28
relationship of imfs and pressure
imfs are strong so it is difficult for it to enter gas phase and so there are fewer molecules of gas which is a lower pressure
29
boiling point and pressure
lower the atmospheric pressure, lower the boiling point
30
critical point
the temperature above which gas cannot be liquified no matter the pressure
31
triple point
condition where all three phases can be present
32
boyles law
p and v are inversely proportional
33
charles law
v and t are directly proportional
34
gay-lussacs law
p and t are directly proportional
35
equilibrium
a dynamic condition in which opposing changes are occurring at the same rate in a closed system
36
equilibrium vapor pressure of a liquid
the pressure exerted by a vapor in equilibrium with its corresponding liquid at a given temperature,,, pressure of a gas above its liquid
37
increase in temperature ___ equilibrium pressure,, why?
increases, because increasing temp increases KE and so more molecules change from liquid to gas, so there are more molecules which means more pressure
38
boiling or evaporation
boiling happens within the liquid while evaporation is just at the surface
39
boiling point
the temperature where the equilibrium vapor pressure equals the surrounding atmospheric pressure
40
what happens to temp when a liquid boils
it stays constant
41
volatile is __ vapor pressure
high vapor pressure == volatile
42
why does increasing atmospheric pressure increase boiling point
more energy is required to boil
43
how can gas pressure be increased
decrease volume, increase temperature, increase amt of gas