Untitled Deck Flashcards
What is the common name for hydrogen chloride?
Muriatic acid
What is the molecular mass (MM) of hydrogen chloride (HCl)?
36.5
What is the vapor density (VD) of hydrogen chloride?
18.25
What are the two chemicals required for the laboratory preparation of hydrogen chloride?
- Sodium Chloride (NaCl) * Concentrated Sulphuric acid (H2SO4)
Why is sodium chloride preferred in the preparation of hydrogen chloride?
It is easily available and cheap.
What happens when sodium chloride reacts with concentrated sulphuric acid at temperatures less than 200°C?
NaCl + H2SO4 → NaHSO4 + HCl
What must be maintained during the reaction to avoid forming a hard crust?
The temperature must be maintained below 200°C.
What occurs if the temperature exceeds 200°C during the preparation of hydrogen chloride?
- Forms a hard crust of sodium sulfate * Glass apparatus may crack
How is dry hydrogen chloride gas collected?
By upward displacement of air.
What is a key characteristic of hydrogen chloride gas regarding its density compared to air?
It is denser than air.
What is the solubility of hydrogen chloride in water?
Highly soluble in water.
What happens when hydrogen chloride gas is dissolved in water?
It creates a partial vacuum in the flask, causing the blue litmus solution to flow upwards.
What color change occurs with blue litmus solution when exposed to hydrochloric acid?
Turns red.
What is the concentration of hydrochloric acid at which it forms a constant boiling mixture?
22.2% HCl at 110°C.
What is the term for a solution that boils without changing its composition?
Azeotrope.
What is the primary ionization reaction of hydrochloric acid in water?
HCl + H2O → H3O+ + Cl-
What is the observation when an active metal reacts with dilute hydrochloric acid?
A colorless gas is evolved which extinguishes a burning splinter with a pop sound.
What occurs when a carbonate reacts with hydrochloric acid?
- Salt * Water * CO2
What gas is evolved when a sulfite reacts with hydrochloric acid?
Sulfur dioxide (SO2).
What type of gas is produced when a sulfate reacts with hydrochloric acid?
- Salt * Water * Sulfur dioxide (SO2)
What is the observation when silver nitrate is added to dilute hydrochloric acid?
A curdy white precipitate of silver chloride is obtained.
Why is concentrated sulphuric acid used in the preparation of hydrochloric acid?
It is a non-volatile acid with a high boiling point that displaces volatile acids.
Why can’t nitric acid be used in the laboratory preparation of hydrochloric acid?
Nitric acid is volatile and may evaporate before hydrogen chloride is formed.
What is the result of using CaO as a drying agent in the preparation of hydrochloric acid?
It reacts with HCl, forming calcium chloride.