VARIABLE OXIDATION STATES Flashcards

TRANSITION METALS (9 cards)

1
Q

What groups can catalysts be divided into? (2)

A

-Heterogeneous
-Homogeneous

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2
Q

What are heterogeneous catalysts?

A

are present in a reaction in a different phase than the reactants, they are usually present as solids whereas the reactants are gases or liquids

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3
Q

how do Heterogenous catalysts act? (1)

A

the reactants pass over the catalyst surface, which remains in place so the catalyst is not lost and does not need to be seperated from the products.

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4
Q

how do industry make catalysts more efficient? (2)

A

-increase their surface area
-spread the catalyst onto an inert support medium, this increase the surface- to mass ratio

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5
Q

How do catalysts become ineffective? (1)

A

over time the surfaces may be covered with unwanted impurities this is called poisoning

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6
Q

what are some examples of heterogeneous catalysts? (2)

A

-the haber process
-the contact process

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7
Q

what are homogenous catalysts? (1)

A

when the catalyst is in the same phase as the reactant, an intermediate species is formed

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8
Q

what is homogenous catalysis by transition metals? (1)

A

the uncatalyzed reaction takes place between two ions of the same charge, both negative which repel, therefore giving a high activation energy. Both steps of the catalysed reaction involve reaction between pairs of oppositely charged ions this explains the increase in rate.

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9
Q

what is autocatalysis? (1)

A

when a product of one of the reactions becomes a catalyst for that reaction.

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