Week 2 (Sulfuric acid) Flashcards

(50 cards)

1
Q

Sulfuric acid is also known as

A

oil of vitriol, vitriol brown oil, mottling acid

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2
Q

Sulfuric acid is a mineral acid composed of the elements

A

hydrogen, sulfur, and oxygen

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3
Q

Sulfuric acid has a _________ solution

A

98 - 99.5%

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4
Q

sulfuric acid can be found in

A

battery acid, electrolytic acid

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5
Q

(true or false)
sulfuric acid is highly corrosive weak mineral acid

A

false
(strong)

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6
Q

sulfuric acid is has a what smell and taste?

A

pungent-ethereal

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7
Q

color of sulfuric acid?

A

colorless to slightly yellow viscous liquid

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8
Q

(true or false)
sulfuric acid is soluble in water at all concentrations

A

true

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9
Q

historical name of sulfuric acid

A

oil of vitriol

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10
Q

sulfuric acid can cause chemical burns via _________

A

hydrolysis

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11
Q

sulfuric acid can cause secondary thermal burns via ______

A

dehydration

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12
Q

sulfuric acid is ______, readily absorbing water vapor from air

A

hygroscopic

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13
Q

Some of the earliest discussions on the origin and properties of vitriol is in the works of the _______ and ________

A

Greek Physician Dioscorides (first century AD)
Roman Naturalist Pliny the Elder (23-79 AD)

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14
Q

he discussed the vitriol’s medical use

A

Galen

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15
Q

Metallurgical uses for vitriolic substances were recorded in the Hellenistic alchemical works of ___________, in the treatise Phisica et Mystica, and the Leyden
papyrus X.

A

Zosimos of Panopolis

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16
Q

Sulfuric acid was called “oil of vitriol” by medieval European alchemists because it
was prepared by roasting _________

A

oil of vitriol (Iron (II) Sulfate)

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17
Q

In the 17th century, he prepared sulfuric acid by burning sulfur together with saltpeter in the presence of steam

A

German-dutch Johann Glauber

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18
Q

In 17th century, German-dutch Johann Glauber prepared sulfuric acid by

A

burning the sulfur together with saltpeter in the presence of steam

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19
Q

saltpeter is

A

Potassium nitrate (KNO3)

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20
Q

as saltpeter decomposes, it oxidizes the sulfur to ____, which combines with water to produce sulfuric acid

A

SO3

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21
Q

In 1736, ______ a london pharmacist, used this method to begin the first large-scale production of sulfuric acid

22
Q

In 1746 in Birmingham, ___________adapted this method to produce sulfuric acid
in lead-lined chambers, which were stronger, less expensive, and could be made larger
than the previously used glass containers.

23
Q

This process allowed the effective industrialization of sulfuric acid production. After several refinements, this method, called the _________, remained the standard for sulfuric acid production for almost 200 years.

A

lead chamber process or chamber
process

24
Q

pyrite or ______

A

iron disulfide (FeS2)

25
________is passed into the lead chamber from glover tower. Afterwards, it is washed using ________
hot sulfur dioxide nitrous vitriol
26
glover acid is approximately ______ sulfuric acid
78%
27
the _________ contains a mixture of gases, such as oxygen, nitrogen, nitrogen oxides, sulfur dioxide, and steam
glover tower
28
The lead chamber has a series of chambers ranging from
3 to 12
29
the gases produced in lead chamber are referred to as a________ and contain between _______ sulfuric acid
chamber acid or fertilizer acid 62 - 68%
30
In 1831, british vinegar merchant _________patented contact process
Peregrine Phillips
31
In 1831, British vinegar merchant Peregrine Phillips patented the ______
contact process
32
it was a far more economical process for producing sulfur trioxide and concentrated sulfuric acid
contact process
33
Sulfur of greater than ________ is used for the production of sulfuric acid
99% purity
34
sulfur is normally present in the ______
flakes or granules
35
it is used for the production of sulfuric acid to avoid difficulties in process equipment
demineral water
36
At proper operating condition, how many mole of water is required for every mole of sulfuric acid
1 mole
37
it is a specially purified water that has had most or all of its mineral and salt ions removed
demineralised water
38
demineralised water is also known as
deionised water, DI, Demin water
39
is usually freer of mineral ions depending on the number of processes used to make it
demineralised water
40
may have less organic contaminants, as deionisation does not removed uncharged molecules such as bacteria or viruses
distilled water
41
leaves behind less scale than distillation, and so has a cleaner production
deionisation
42
the contact process relies on _______ for the manufacture of sulfuric acid
elemental sulfur
43
Sulfur dioxide is obtained by roasting the respective _________ in air
metal sulfide ores (PbS-Galena)
44
The conversion of sulfur dioxide to sulfur trioxide is an
exothermic reaction
45
The reactor has four beds of catalysts referred to as a ________
converter
46
in conversion of sulfur dioxide to sulfur trioxide takes place in the presence of _______
Vanadium (V) oxide (V2O5)
47
______are added to function as promoters thereby lowering the melting point of the catalyst
cesium pellets
48
when sulfur trioxide is first absorbed into concentrated sulfuric acid, it results in the formation of ______
oleum
49
grades of sulfuric acid 10% ______ 29 - 32% _____ 62 - 70% ______ 78 - 80% _____ 98% ______
dilute sulfuric acid battery acid chamber acid/ fertilizer acid tower/ glover acid concentrated sulfuric acid
50
diprotic means
can donate two protons