Week 3 Quantum Flashcards
(37 cards)
Why is the wave function not a de broglie particle? (5 points)
- Can be complex
- Can be infinitive
- Hamilton can be infinite until x goes to infinity (tend to measure infinite particles)
- One wave function can describe many particles
- Exists in space with more than 3 dimensions (space and time)
Born rule
Psi squared - probability of finding a particle at position x
Wavefunction provides
All information required to make predictions about system
Can you measure wavefunctions?
No because can only measure real numbers
Infinite square well wavefunction
B cos (pi x/ 2a)
Infinite square well wavefunction
B cos (pi x/ 2a)
Mean position
Integral of x * psi^2
TIWE with expansion coefficient
Sum of Cn Psi n
TDWE with expansion coefficient
Sum of Cn Psi n e^ -(i En t/ h bar)
Wave function Psi n x Psi m
0 if n does not = m, 1 if n=m due to orthognality
Physical significance of expansion coefficients
Cn squaed =probability of measuring En
Cn
Expansion coefficient = integral of Psi x Psi*
Sum of Cn squared
=1
Eigenfunction
Wavefunction defining state where observable has known, defined value
Eigenvalue
Value of observable physical parameter in eigenstate
Eigenstate
State of a system where observable has known value
Probability of being in ground state
Probability of being in C1 = C1 squared
Find all Cn (7 steps)
- Find any constants in wave function E.g. A
- Now define Wavefunction (WF)
- Cn = Psi n x WF
- Divide into Psi odd and Psi even (odd cos, sin even)
- Cn odd = integral of WF x (1/sqrt a) cos (n pi x/ 2a)
- Cn even = integral of WF x (1/sqrt a) sin (n pi x/2a)
- Therefore Psi = Cn written in individual surviving terms…
Momentum operator
Px = - i hbar d/dx
The eigenfunctions depend on…
The observables. There are different eigenfunctions for each observable but all included in wave function
Discrete vs continuous variables…
Exponential: Discrete =n, continuous = k
Operator for position
X
How to find E1 - two options
- Hamilton operator on Wavefunction
- = whatever is in front of integral of Wavefunction squared
OR c1 squared
Expectation value of ISqW
Integral of position, operator x psi squared