Week 7 Flashcards

(34 cards)

1
Q

What drives vertical mixing in the ocean?

A

Buoyancy, determined by temperature and salinity.

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2
Q

Where does deep water formation occur and why?

A

In polar regions, where surface water is cold and salty (dense and heavy).

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3
Q

Why is vertical mixing suppressed in most ocean regions?

A

Surface water is warmer (less dense) than deeper water.

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4
Q

What causes vertical mixing in the surface ocean?

A

Wind stress creates a mixed layer ~100 m deep.

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5
Q

What are the residence times of water in ocean reservoirs?

A

Mixed layer: 18 years

Intermediate ocean: 40 years

Deep ocean: 120 years

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6
Q

How long does it take for the entire ocean to equilibrate with atmospheric CO₂?

A

About 200 years.

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7
Q

How much fossil fuel CO₂ can the oceanic mixed layer absorb directly?

A

Only ~6%.

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8
Q

What controls fossil fuel CO₂ uptake by oceans?

A

Rate of deep water formation and surface mixing.

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9
Q

How does phytoplankton contribute to CO₂ uptake?

A

Through photosynthesis and forming organic carbon.

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10
Q

What happens to the organic carbon produced by phytoplankton

A

90% is respired/decayed back to CO₂(aq)

10% sinks (biological pump) to deep ocean.

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11
Q

What limits biological productivity in surface oceans?

A

Nutrient supply from deep ocean (upwelling), especially nitrogen.

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12
Q

How much carbon does the biological pump transfer yearly?

A

~7 Pg C yr⁻¹

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13
Q

How much CO₂(aq) is transported by deep water formation per year?

A

~40 Pg C yr⁻¹

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14
Q

How much fossil fuel CO₂ is absorbed by oceans?

A

About 30%.

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15
Q

CO2 seasonal cycle- summer- northern hemisphere

A

CO2 drops as plants absorb CO2 during growth

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16
Q

CO2 seasonal cycle- winter- northern hemisphere

A

microbes decompose organic matter releasing CO2

17
Q

How is ocean alkalinity maintained?

A

Weathering of basic rocks followed by river run off

18
Q

How does a decrease in pH due to ocean acidification

A

Oceans absorb less CO2

19
Q

Impact of rising NPP on CO2 sinks

A

Rises in forest regrowth and waeming may increase the sink of CO2

20
Q

What is deposition controlled by?

A

Solubility of species in water-wet
Amount of precipitation-wet
Terrain and type of surface cover-dry

21
Q

Factors determining dry deposition

A
  • Atmospheric tubulence -governs rate of species delivered to surface
    *Chemical properties of depositing species e.g. reactivitt
  • Nature and reactivity of surface
22
Q

Vertical dry deposition flux- equation

A

F=-vdC
= - Deposition velocity * Local concentration at reference height

23
Q

How is dry deposition decribed?

A
  1. Aerodynamic transport down through atmopsheric surface
  2. Molecular (Brownian) transport for gases across the quasi-laminar sublayer to the surface
    3.Uptake at the surface
24
Q

Dry deposition resistance model- ra

A

Aerodynamic resistance- ra= tranport occurs by turbulent diffusion (surface layer)

25
Dry deposition resistance model- rb
Quasi laminar layer resistance- Transport occurs by diffusion - removal can happen by interception when particles collide w obstacles
26
Dry deposition resistance model- rc
Canopy resistance- Gaseous species uptake can be irreversible into the surface; particles adhere. For soluble species any surface surface moisture can have a marked effect on removals
27
2 main processes of wet depositon
Rainout and washout
28
2 main sources of acid rain deposition
Nitric acid (NOx oxidation) and Sulphuric acid (SO2 oxidation)
29
Impact of acid rain on vegetation
Yellowing of leaves/needles Needle loss Tree death
30
How can rain's acidity be buffered?
Ammonia from biosphere or CaCO3 from soil dust
31
Main air pollutants
Ozone-O3 Particulate matter-PM2.5 NO2
32
Primary Air Pollutants?
Sulfur Dioxide (SO₂) Nitrogen Monoxide (NO) Carbon Monoxide (CO) Particulate Matter (PM₁₀, PM₂.₅) Volatile Organic Compounds (VOCs)
33
Secondary Air Pollutants?
Ozone (O₃) Sulfuric Acid (H₂SO₄) Aerosols Peroxyacyl Nitrates (PAN) Secondary Particulate Matter (PM₂.₅) Nitric Acid (HNO₃)
34