Week 7- fundamental concepts of enamel and dentin adhesion Flashcards

1
Q

fundamental mechanism of enamel resin adhesion

A

formation of resin microtags in enamel surface

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2
Q

enamel adhesion made possible by

A

acid etch which makes enamel surface irregular

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3
Q

purpose of acid etch

A

makes enamel surface irregular -> resin penetrates surface -> polymerize and are then attached to enamel

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4
Q

the state in which two surfaces are held together by interfacial forces that consist of valence forces, interlocking forces, or both

A

adhesion

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5
Q

4 mechanisms of adhesion

A
mechanical 
adsorption
diffusion
electrostatic
(MADE)
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6
Q

mechanical adhesion

A

interlocking of adhesive with irregularities in surface of substrate or adherend (enamel?)

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7
Q

absorption adhesion

A

chemical bonding between adhesive and adherend forces
primary (ionic, covalent)
secondary (H bonds)
valence forces

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8
Q

diffusion adhesion

A

between mobile molecules such as adhesion of two polymers through diffusion of polymer chain ends across interface

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9
Q

electrostatic adhesion

A

electrical double layer at interface of a metal with a polymer that is part of total bonding mechanism

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10
Q

4 types of dental adhesion

A

mechanical
adsorption
diffusion
combination of the above

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11
Q

microtags

A

small tags form across end of each rod

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12
Q

macrotags

A

tags form between enamel rods

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13
Q

what differentiates GI from resin based composite materials?

A

do not need to etch enamel/dentin with phosphoric acid gel

“self adhesive”

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14
Q

mechanical dental adhesion

A

penetration of resin and formation of resin rags with tooth structure

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15
Q

adsorption dental adhesion

A

chemical bonding to inorganic component (HA) or organic components (collagen I) of tooth structure

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16
Q

diffusion dental adhesion

A

precipitation of substances on tooth surface to which resin monomers can bond chemically or mechanically

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17
Q

what is critical for good adhesion?

A

close contact between adhesive and substrate (enamel or dentin)

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18
Q

adhesive failure

A
  1. cohesive failure in substrate
  2. cohesive failure within adhesive
  3. adhesive failure @ interface of substrate and adhesive
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19
Q

adhesive restoration technique uses

A
17 different things
bonding, sealing, recontouring of teeth, 
improve retention for PftM or metallic crowns
bond all ceramic restorations 
cavity restorations (class I-VI)
bond ortho brackets & perio splints
desensitize exposed root surfaces
repair existing restorations
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20
Q

morphological patterns of acid etching - type I

A

dissolution of prism cores but keep prism peripheries

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21
Q

morphological patterns of acid etching - type II

A

dissolution of prism peripheries but keep cores

22
Q

morphological patterns of acid etching - type III

A

not related to prism morphology

23
Q

phosphoric acid concentration for etching

24
Q

etching time

A

15-60 seconds

25
bond strength
20-50 MPa
26
low end estimate of bond strength to resist contraction stresses
17MPa
27
Dentin adhesion relies on
penetrations of adhesion monomers into collaged network left exposed by acid etching
28
what makes etching dentin difficult?
dentin tubules with collagen and liquid
29
smear layer
after preparing tooth structure, remaining residual organic and inorganic components form layer of debris that fills dentin tubule orifices removal results in fluid flow into exposed dentin - interferes with adhesion
30
ratio between # bonded surfaces and unbonded surfaces
Configuration (C) factor
31
stress relief within a 3D bonded restoration is limited by its
C-factor
32
class I restoration C-factor
5 ; results in stress relief due to limited flow from only one free surface
33
what may act to offset polymerization shrinkage effects?
water absorption by resin
34
microleakage around dentin margins is potentiated by
difference in linear coefficient of thermal expansion between substrate (tooth) and restoration
35
improves enamel seal:
extension of cavosurface bevel of enamel
36
______ usually sufficient to prevent formation of marginal gaps by polymerization contraction stresses
enamel bond strengths
37
loading and unloading of restored teeth can lead to:
damage or marginal gaps
38
how to remove smear layer?
acid etch
39
options for resin-dentin bonding
3 step etch and rinse adhesives 1. phosphoric acid etching gel, rinse 2. primer containing reactive hydrophilic monomers in ethanal, acetone, or water 3. unfilled/filled resin bonding agent
40
acid etch acts to
remove smear layer demineralize intertubular and peritubular dentin expose filigree of collagen fibers
41
it is desirable for substrate to have ______ surface energy
high
42
after etching, dentin is left with ______ surface energy
low
43
what effect does primer in 3 step process have?
increases surface tension of dentin
44
what happens when primer and bonding resin applied?
penetrate intertubular dentin and form resin-dentin interfusion hybrid zone and resin tags = good bonding
45
two step etch and rinse adhesive
1. etch | 2. primer and adhesive in same bottle
46
water trees associated with:
porosities in adhesive layer
47
microleakage
passage of bacteria and toxins between restoration margins and tooth prep walls bacteria can lead to pulpal irritation
48
interfacial gap
develops when dentin adhesive system does not adhere immediately to dentin substrate bacteria can penetrate this gap
49
when all restoration margins are in enamel, quality and integrity of the bond remain:
unchanged OR degraded by hydrolysis
50
nanoleakage
small porosities in hybrid layer or hybrid/mineralized dentin transition layer allow penetration of little particles of silver nitrate dye
51
``` spotted pattern in hybrid layer or reticular pattern in adhesive layer (the RA says SHhhh) result from: ```
nanoleakage