Year 12 Aliphatic Flashcards

(34 cards)

1
Q

Name for long chain hydrocarbons into alkenes

A

Thermal cracking

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2
Q

Conditions for thermal cracking

A

High temperature
High pressure

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3
Q

Name for long chain hydrocarbons into aromatics/cyclic alkanes/branched alkanes

A

Catalytic cracking

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4
Q

Reagents and conditions for catalytic cracking

A

Zeolite catalyst and moderate temperatuee

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5
Q

Mechanism for alkane into haloalkane

A

Free radical substitution

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6
Q

Regents and conditions for catalytic cracking

A

X2 and UV light

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7
Q

Mechanism for haloalkanes into alcohol

A

Nucleophilic substitution

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8
Q

Regents and conditions for nucleophilic substitution into an alcohol

A

NaOH (:OH-)
Aqueous, heat under reflux

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9
Q

Mechanism for haloalkanes into nitrile

A

Nucleophilic substitution

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10
Q

Reagents and conditions for nucleophilic substitution into a nitrile

A

KCN (:CN-)
Ethanolic, heat under reflux

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11
Q

Mechanism name for haloalkanes into amine

A

Nucleophilic substitution

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12
Q

Reagents and conditions for nucleophilic substitution into amines

A

Excess of concentrated NH3
Ethanol solvent, heat under pressure

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13
Q

Mechanism name for haloalkanes into alkenes

A

Basic elimination

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14
Q

Reagents and conditions for basic elimination

A

KOH/NaOH in ethanol
Hot and ethanolic for the :OH to act as a base

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15
Q

Mechanism name for alkene into haloalkanes

A

Electrophilic addition

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16
Q

Reagents and conditions for electrophilic addition into haloalkanes

A

HBr
Room temp

17
Q

Mechanism name for alkene into dihaloalkane

A

Electrophilic addition

18
Q

Reagents and conditions for electrophilic addition into a dihalolkane

19
Q

Mechanism name for alkene into hydrogen sulfate

A

Electrophilic addition

20
Q

Reagents and conditions for electrophilic addition into hydrogen sulfate

21
Q

Mechanism name for alkene into an alcohol

22
Q

Reagents and conditions for hydration

A

H2O and a phosphoric acid catalyst
High temperature and pressure

23
Q

Name for glucose into ethanol

24
Q

Reagents and conditions for fermentation

A

Yeast catalyst
Anaerobic

25
Mechanism for alcohol into alkene
Elimination
26
Reagents and conditions for elimination
Concentrated sulfuric/phosphoric acid Heat under refluc
27
Name for primary alcohol into aldehyde
Oxidation
28
Reagents and conditions for oxidation into an aldehyde
Acidified potassium dichromate Heat under distillation
29
Name for primary alcohol into carboxylic acid
Oxidation
30
Reagents and conditions for primary alcohol into carboxylic acid
Excess acidified potassium dichomrate Heat under relfuc
31
Name for secondary alcohol into a ketone
Oxidation
32
Reagents and conditions of oxidation into aromatics ketone
Acidified potassium dichromate Heat
33
Name for aldehyde into carboxylic acid
Oxidation
34
Reagents and conditions for oxidation of any aldehyde into a carboxylic acid
Acidified potassium dichomrate Heat under reflux