01 Matter & Energy Flashcards

(70 cards)

1
Q

What is a subatomic particle

A

Particles that are smaller than an atom; among such particles protons, neutrons, and electrons are of special significance in chemistry

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2
Q

What are atoms composed of

A

Protons and neutrons held in the nucleus surrounded by an electron cloud

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3
Q

How are electrons and protons held together

A

By an attractive electrostatic force

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4
Q

Coulomb’s law

A

The force of interaction between two charged particles Q1 and Q2 is directly proportional to the product of the two charges and inversely proportional to the distance (d) between the charges squared, where k is the coulomb constant
F = k(Q1Q2/d^2)

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5
Q

What is an isotope

A

Atoms with the same atomic number but different number of neutrons

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6
Q

What are a, z and x standing for
A
X
Z

A

A: Mass number (protons + neutrons)
Z: Atomic number (protons)
X: atomic symbol

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7
Q

What is atomic weight

A

Average of the masses of all isotopes present
AW = (isotope mass) x (fractional natural abundance)

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8
Q

What is the law of conversion of mass

A

No atoms can be transformed into other atoms, and no atoms may be destroyed or created
- in chemical reactions the nuclei of atoms is unchanged

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9
Q

What is avgardos number

A

A conversion factor for relating grams to atomic mass units
The number of atoms in exactly 12g of carbon-12 is equal to 6.022 x 10^23: the number of particles in a mole of any surface

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10
Q

What is a mole

A

A collection containing avogadros number of objects

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11
Q

What is an anion

A

A negatively charged ion
(Gained an electron/s)

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12
Q

What is a cation

A

A positively charged ion
(Lost electrons)

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13
Q

Atoms combine to form…

A

Molecules or extensive solids

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14
Q

Molecular Compounds

A

A compound composed of atoms of two or mo

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15
Q

What is energy

A

The capacity to do work and transfer heat or the ability to make something happen

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16
Q

Potential energy

A

Related to the positioning of an object in relation to other objects

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17
Q

Kinetic

A

Related to the motion of objects

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18
Q

First law of thermodynamics

A

Energy can be converted from one form to another, but cannot be created or destroyed (aka law of energy conversion)

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19
Q

Electrostatic

A

Relating to interactions (force and energy) of stationary charges or fields

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20
Q

Which energies dominate chemical processes

A

Kinetic energy of particle motion and electrostatic potential energy

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21
Q

Types of potential energy

A

Electrostatic, nuclear, or gravitational energy

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22
Q

What does the change in internal energy of a system result from

A

The exchange of heat or work with the surroundings

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23
Q

Internal energy of a system

A

The total energy associated with the system, the sum of all sources of kinetic and potential energy

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24
Q

Internal energy changes (ΔE)

A

(Usually more important)
Directly connected to a physical or a chemical process under consideration

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25
Internal energy changes formula
ΔE = q + w
26
-q
Removing heat from a system
27
-w
Having the system do the work
28
ΔE > 0
Q > 0 - heat is added to the system W > 0 - work is done on the system
29
ΔE < 0
Q < 0 - heat is removed from the system W < 0 - work is done by the system
30
What is a state function
Property that depends only on its present state of the system, and is independent of how the state was achieved Examples: P(pressure), T(temperature), E(internal energy), and H(enthalpy) Capital letters are used for state functions
31
What is enthalpy
The heat exchanged with the surroundings under constant pressure
32
In chemical and physical changes occuring under constant pressure, it is indeed quite common that the only work done by that system is due to…
Volume change
33
Endothermic
ΔH > 0 A process in which the system absorbs heat Q > 0
34
Exothermic
ΔH < 0 Heat transfers to the surroundings Q < 0
35
What is light
An electromagnetic wave The “purest” form of energy as it may exist “outside” of matter - on one hand it is an electromagnetic wave traveling with an enormous speed - on the other hand it interacts with matter as a stream of energy packets or photons
36
What is a quantum
The smallest possible amount of a distinct quality
37
Wavelength
The distance between two adjacent peaks or troughs
38
The maximum amplitude of the waves is..
A measure of intensity of the radiation
39
What is radiation
The emission and transmission of energy through space in the form of electromagnetic waves
40
Frequency (v)
The number of cycles that pass a given point per second Expressed as cycles per second or in hertz
41
Properties of waves depends on
Their wavelengths
42
Wavelength range of the visible light spectrum
400-750 nm
43
Photons
What light is a stream of Quantized energy packets
44
Waves in order of increasing wavelength
Gamma rays < x-rays < UV rays < visible light < infrared < microwave < radio
45
Which is more energetic, long waves or small waves
Short waves (large frequency)
46
What is the photoelectric effect
The phenomenon in which only light of proper frequency can eject electrons from an illuminated metal surface
47
What is black body radiation
When solids are heated they emit radiation. The distribution of wavelengths of these electromagnetic waves depends on the temperature of the solid - lower temps: infared frequencies - increasing temps: starts emitting visible light - brown -> red->orange->yellow->white
48
What do BBR and TPEE illustrate
That light can exhibit a “corpuscular” nature in its interaction with nature
49
What is spectroscopy
The study of how light interacts with matter
50
How does light interact with a clear object
All wavelengths of light are transmitted
51
How does light interact with a colored solution
The light of that color is transmitted and the waves of the light of the color absorbed by the medium
52
How does light interact with an opaque material
It reflects the wavelengths
53
What happens when light is emitted
Wavelengths are given off by the system
54
What is a spectrophotometer
A tool used to measure the absorption of light
55
Light energy absorbed by atoms or molecules is converted into…
Various forms of kinetic or potential energy
56
Changes that occur when gamma rays are absorbed
Ionizes atoms and molecules, breaks chemical bonds
57
Changes that occur when x-rays are absorbed
Ionizes atoms and molecules, breaks chemical bonds
58
Changes that occur when UV rays are absorbed
Ionizes atoms and molecules, breaks chemical bonds, promotes electrons to higher energy
59
Changes that occur when visible light is absorbed
Promotes electrons to higher energy
60
What changes occur when infrared rays are absorbed
Increases amplitude of vibrations
61
Changes that occur when microwaves are absorbed
Increases speed of molecular rotations
62
Changes that occur when radio waves are absorbed
Flips the nuclear spin
63
What is the only way that the earth can transfer energy back to space
Radiation
64
About how much incoming light is reflected back, out of the system into space
30%
65
What percentage of incoming light is absorbed by molecules in the atmosphere
19%
66
What percentage of incoming light reaches earths surface
51%
67
What is the greenhouse effect
The “trapping” of energy close to the surface due to greenhouse
68
What is global warming
A gradual increase in the average temperature of the earth due to an imbalance in earths energy cycle
69
When a component color is absorbed by an object, what color does the object appear to be
The complementary color
70
As temperature increases…
Increases: peak frequency, energy of the photon and light intensity Decreases: peak wavelength